Ferroelectric Capacitor Waste Heat Conversion via Phase Transitions

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Solution Overview

Problem

Industrial processes often lose energy as waste heat, which is not efficiently converted into usable electricity.

Innovation Solution

A power generation system utilizing a dielectric material that transitions between ferroelectric and paraelectric/antiferroelectric phases with temperature changes, cyclically heating and cooling to induce electric current through capacitors and an electric load, effectively converting waste heat into electricity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional heat conversion methods are used, then energy conversion can occur, but the conversion efficiency is low and waste heat is not effectively utilized

Engineering Contradiction:
Improvewaste heat lossVSAvoidelectricity generation efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent utilizes the phase transition of ferroelectric materials between ferroelectric and paraelectric states at the Curie temperature. During heating above the Curie temperature, the material transitions to a paraelectric state with reduced dielectric constant, causing charge to flow from the capacitor to the reference. During cooling below the Curie temperature, the material transitions back to a ferroelectric state with increased dielectric constant, causing charge to flow from the reference capacitor. This phase transition mechanism enables efficient conversion of waste heat into electrical energy, directly addressing the low efficiency problem of conventional heat conversion methods.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The patent exploits changes in the dielectric constant parameter of ferroelectric materials as temperature changes. The dielectric constant increases significantly when the material transitions from paraelectric to ferroelectric phase below the Curie temperature, and decreases when transitioning to paraelectric phase above the Curie temperature. This parameter change enables the capacitor to store and release charge cyclically, converting thermal energy into electrical energy with high efficiency and effectively utilizing waste heat that would otherwise be lost.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If ferroelectric materials are used for heat to electricity conversion, then conversion efficiency improves, but the system complexity increases due to temperature cycling requirements

Engineering Contradiction:
Improveelectricity generation efficiencyVSAvoidtemperature cycling system complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent employs a reference capacitor that automatically charges and discharges in response to the dielectric material's phase transitions, without requiring external control mechanisms. The reference capacitor passively receives charge during the ferroelectric phase transition and releases charge during the paraelectric phase transition, enabling the system to self-regulate the electricity generation process. This self-service approach reduces system complexity while maintaining high conversion efficiency, as the temperature cycling is driven by the waste heat source itself rather than requiring complex external temperature control systems.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This system efficiently converts waste heat into electricity by leveraging the phase transitions of ferroelectric materials, enabling the generation of electric power from small temperature fluctuations and improving energy efficiency in various industrial and mechanical processes.

Implementation Method 1

The dielectric material is configured to transition from a ferroelectric phase to a paraelectric or antiferroelectric phase when heated above a first transition temperature. The dielectric material is also configured to transition from the paraelectric or antiferroelectric phase to the ferroelectric phase when cooled below a second transition temperature.

Methodology Applied
Scientific EffectFerroelectric phase transition: Phase Change

Implementation Method 2

heat the dielectric material beyond the first transition temperature, such that a charge is drawn from the first capacitor to the second capacitors through the electric load

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

cyclically cool the dielectric material below the second transition temperature, such that a charge is drawn from the second capacitor to the first capacitors through the electric load

Methodology Applied
Scientific EffectThermal cooling: Cooling

Data Source

PatentUS10950777B2Conversion of heat to electricity using phase transformations in ferroelectric oxide capacitors
Publication Date: 2021.03.16 REGENTS OF THE UNIVERSITY OF MINNESOTA
  • US10950777B2 patent drawing
  • US10950777B2 patent drawing

AI summary

An example power generation system includes two capacitors and an electric load. A first capacitor includes a dielectric material that is configured to transition from a ferroelectric phase to a paraelectric or antiferroelectric phase when heated above a first transition temperature, and to transition from the paraelectric or antiferroelectric phase to the ferroelectric phase when cooled below a second transition temperature. A second capacitor is electrically coupled in parallel to the first capacitor. The electric load is electrically coupled to the first capacitor and the second capacitor. The system is configured to cyclically cool the dielectric material below the second transition temperature to draw a charge from the second capacitor to the first capacitors through the electric load, and heat the dielectric material beyond the first transition temperature to draw a charge from the first capacitor to the second capacitors through the electric load.