Ferroelectric Memory Cell Crystal Orientation Control

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Solution Overview

Problem

Ferroelectric field-effect transistors based on binary oxide ferroelectrics suffer from significant device-to-device variation in memory states due to random crystal orientations of the ferroelectric film, leading to inconsistent threshold voltage shifts and memory state encoding.

Innovation Solution

The integration of a polycrystalline or monocrystalline ferroelectric film with crystal grains oriented along a predetermined axis, or the use of crystallinity-promoting layers to enhance the crystal structure, reduces device-to-device variation by promoting homogeneous crystal growth and alignment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a polycrystalline ferroelectric film with random crystal orientations is used, then the manufacturing process is simple, but the device-to-device variation of memory states is significant

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoiddevice-to-device variation of memory states
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the crystallographic orientation parameter of the ferroelectric film from random to aligned along a predetermined axis. This is achieved by controlling the deposition process parameters (temperature, pressure, gas flow ratios) and using crystallinity-promoting layers with specific crystal structures that template the desired orientation, thereby reducing device-to-device variation while maintaining manufacturing feasibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces an intermediary crystallinity-promoting layer between the substrate and the ferroelectric film. This layer has a crystal structure that promotes the growth of the ferroelectric film with aligned crystal grains along a predetermined axis, acting as a template that mediates between the random substrate and the desired ordered ferroelectric structure

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If the crystal grains of the ferroelectric film are aligned along a predetermined axis, then the device-to-device variation of memory states is reduced, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvedevice-to-device variation of memory statesVSAvoidcrystal structure control complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies deposition parameters including temperature (400-700°C), pressure (20-1000 mTorr), and gas flow ratios (O2/Ar or O2/N2 between 10-90%) to promote crystalline growth with aligned grains. These parameter changes enable crystal orientation control without requiring additional complex processing steps

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by using crystallinity-promoting layers with specific crystal structures at the interface with the ferroelectric film. The local crystal structure at the interface promotes aligned grain growth in the overlying ferroelectric film, while the rest of the device structure remains conventional

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly decreases statistical device-to-device variation of memory states in ferroelectric memory cells, improving the reliability and consistency of memory state encoding in ferroelectric field-effect transistors and capacitors.

Implementation Method 1

The ferroelectric film is a polycrystalline film having a plurality of crystal grains, wherein the crystal grains are oriented along a predetermined crystal axis, or that the ferroelectric film is a monocrystalline film, wherein the ferroelectric film comprises additives promoting formation of the crystal structure of the monocrystalline film

Methodology Applied
Scientific EffectCrystallisation: Crystallisation

Data Source

PatentUS10872905B2Integrated circuit including a ferroelectric memory cell and manufacturing method thereof
Publication Date: 2020.12.22 NAMLAB GGMBH
  • US10872905B2 patent drawing
  • US10872905B2 patent drawing
  • US10872905B2 patent drawing

AI summary

An integrated circuit comprises a ferroelectric memory cell comprising a ferroelectric film comprising a binary oxide ferroelectric with the formula XO2 where X represents a transition metal. The ferroelectric film is a polycrystalline film having a plurality of crystal grains, wherein the crystal grains are oriented along a predetermined crystal axis, or the ferroelectric film is a monocrystalline film, wherein the ferroelectric film comprises additives promoting formation of the crystal structure of the monocrystalline film and/or wherein the memory cell comprises a crystallinity-promoting layer that is directly in contact with the ferroelectric film and promotes formation of the crystal structure of the monocrystalline film.