Ferroelectric Memory Edge Defect Repair via Healing and Block Layers

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Solution Overview

Problem

Existing ferroelectric memory device fabrication processes result in edge defects due to etching and ion implantation, leading to crystalline defects, contamination, and material degradation, which impair the performance by increasing leakage current and reducing capacitance.

Innovation Solution

A ferroelectric memory device with reduced edge defects is achieved by forming a doped portion in the defective edge region to repair the crystalline structure, using a healing layer to passivate the edges, and a block layer to prevent contaminants, along with thermal annealing and diffusion methods to further reduce defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If etching and ion implantation processes are used during fabrication, then the ferroelectric memory device can be manufactured with standard semiconductor processes, but edge defects, crystalline defects, and contamination occur that increase leakage current and reduce capacitance

Engineering Contradiction:
Improvefabrication process compatibilityVSAvoidedge defect reduction
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent extracts and removes the defective edge region of the ferroelectric layer through selective etching, separating it from the functional memory region. This extraction eliminates the source of leakage current while preserving the bulk ferroelectric properties, directly resolving the contradiction between manufacturability and reliability.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent introduces an intermediary layer between the electrode and the ferroelectric layer at the edge region. This intermediary structure acts as a mediator that prevents direct contact between the electrode and defective ferroelectric edges, reducing leakage current while allowing the standard fabrication process to continue.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If the ferroelectric layer edges are exposed during fabrication, then the device structure can be formed, but the exposed edges suffer from contamination and material degradation

Engineering Contradiction:
Improvestructural formationVSAvoidedge contamination
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary protective measures to the ferroelectric layer edges before contamination can occur. By forming protective structures and applying protective atmospheres during fabrication, the patent prevents contamination and material degradation at the exposed edges, resolving the contradiction between structural formation and contamination prevention.

Inventive Principle:
Principle #9Preliminary anti-action

Solution Approach 2:

The patent employs an inert atmosphere during fabrication processes to protect the exposed ferroelectric layer edges from contamination. This inert environment prevents harmful chemical reactions and material degradation, allowing the device structure to be formed without edge contamination.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Manufacturing precision

If thermal annealing is applied to repair crystalline defects, then the ferroelectric layer crystallization is enhanced, but additional process steps and time are required

Engineering Contradiction:
Improvecrystalline structure qualityVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent performs preliminary actions during the main fabrication process to prevent crystalline defects from forming in the first place. By controlling deposition conditions and using protective measures during fabrication, the patent reduces the need for subsequent thermal annealing, thereby maintaining high crystalline quality while minimizing additional processing time.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach significantly improves the performance of ferroelectric memory devices by reducing edge defects, enhancing crystallization, and stabilizing the lattice, thereby minimizing leakage current and maintaining capacitance.

Implementation Method 1

using a healing layer to passivate the edges

Methodology Applied
Scientific EffectPassivation:

Implementation Method 2

along with thermal annealing and diffusion methods to further reduce defects

Methodology Applied
Scientific EffectThermal annealing: Annealing

Implementation Method 3

forming a doped portion in the defective edge region to repair the crystalline structure

Methodology Applied
Scientific EffectDoping: Dopants

Implementation Method 4

a block layer to prevent contaminants

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS11839087B2Ferroelectric memory devices with reduced edge defects and methods for forming the same
Publication Date: 2023.12.05 WUXI SMART MEMORIES TECHNOLOGIES CO LTD
  • US11839087B2 patent drawing
  • US11839087B2 patent drawing
  • US11839087B2 patent drawing

AI summary

Embodiments of ferroelectric memory devices and methods for forming the ferroelectric memory devices are disclosed. In an example, a ferroelectric memory cell includes a first electrode, a second electrode, and a ferroelectric layer disposed between the first electrode and the second electrode. An edge region exposed by the first electrode and the second electrode is covered by at least one of a healing layer or a block layer.