Ferroelectric OFET Arrays With Piezoelectric Charge Amplification

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Solution Overview

Problem

Existing thin film semiconductor technologies, particularly organic field-effect transistors (OFETs), face challenges in scalable and cost-effective production, flexibility, and efficient charge sensing and amplification, especially in large-area applications, due to limitations in substrate compatibility and parasitic capacitive loading in active matrix architectures.

Innovation Solution

The development of OFET systems with ferroelectric gate dielectrics for electrical reprogramming and piezoelectric substrates for local amplification, combined with roll-printing techniques, allows for the construction of electrically programmable arrays and direct measurement of trap distribution and grain structure, enabling flexible and scalable electronics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional thin film semiconductor technologies are used, then manufacturing process is established, but scalability and cost-effectiveness are limited

Engineering Contradiction:
ImprovescalabilityVSAvoidcost-effectiveness
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent changes the material parameters by using organic semiconductors instead of conventional inorganic materials, enabling low-temperature processing and flexible substrate compatibility. This parameter change allows for scalable production through solution-based techniques while maintaining cost-effectiveness through simplified manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures combining organic semiconductors with flexible substrates and specialized dielectric layers. This composite approach enables both scalability through roll-to-roll processing and cost-effectiveness by using organic materials that can be deposited via low-cost solution techniques rather than expensive vacuum deposition.

Inventive Principle:
Principle #40Composite materials

2Strength

If conventional substrates are used, then structural support is provided, but flexibility is limited

Engineering Contradiction:
Improvestructural supportVSAvoidflexibility
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent replaces conventional rigid substrates with flexible thin film structures, including organic dielectric layers and flexible support substrates. This enables the device to bend and conform to curved surfaces while maintaining structural integrity, achieving both flexibility and adequate structural support through the engineered thin film stack.

Inventive Principle:
Principle #30Flexible shells and thin films

3Device complexity

If charge sensing is implemented without local amplification, then device structure is simple, but charge detection precision is insufficient

Engineering Contradiction:
Improvedevice structureVSAvoidcharge detection
Core Design Contradiction:
Device complexityVSMeasurement precision

Solution Approach 1:

The patent introduces an intermediary piezoelectric layer between the charge source and the sensing electrode. This piezoelectric intermediary converts mechanical stress from charge accumulation into electrical signals, providing local charge amplification that enhances detection precision while adding only a single functional layer to the device structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Measurement precision

If piezoelectric substrate is used for local amplification, then charge detection is enhanced, but parasitic capacitive loading increases

Engineering Contradiction:
Improvecharge detectionVSAvoidparasitic capacitive loading
Core Design Contradiction:
Measurement precisionVSObject-generated harmful factors

Solution Approach 1:

The patent applies the piezoelectric effect locally at specific sensing regions rather than across the entire substrate. By confining the piezoelectric material to localized areas where charge detection is needed, the device achieves enhanced charge detection precision at those specific points while minimizing the total parasitic capacitive loading that would result from using piezoelectric material across the full substrate area.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of flexible, cost-effective, and scalable electronic devices with improved charge sensing and amplification capabilities, suitable for large-area applications, such as two-dimensional arrays and active matrix piezoelectric devices, enhancing detection sensitivity and reducing parasitic effects.

Implementation Method 1

A poled piezoelectric substrate. A conductive field-effect transistor (FET) gate is formed on the substrate... locally amplify a piezoelectric-generated charge, sensed at the gate from an local region of the substrate that is adjacent to the gate

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

An organic ferroelectric gate dielectric is formed on the gate and on the substrate near the gate, and configured to permit electrically programmable adjustment of a FET threshold voltage

Methodology Applied
Scientific EffectFerroelectric effect:

Data Source

PatentUS20080309412A1Organic field effect transistor systems and methods
Publication Date: 2008.12.18 THE TRUSTEES OF COLUMBIA UNIV IN THE CITY OF NEW YORK
  • US20080309412A1 patent drawing
  • US20080309412A1 patent drawing
  • US20080309412A1 patent drawing

AI summary

An OFET includes a ferroelectric gate dielectric permitting electrical reprogramming, such as to implement an electrically re-programmable array logic (PAL) or a field-programmable gate array (FPGA). Methods of constructing such an OFET, PAL, or FPGA, can including roll printing. An OFET on a piezoelectric substrate provides local amplification in an active matrix. Methods of constructing such an OFET on a piezoelectric substrate can including rolling printing. Techniques permit direct measurement of trap distribution, such as across the channel length of an OFET device. Techniques permit direct measurement of the size and location of an electrically active grain structure in OFET devices. Techniques permit confirmation of the mechanism of operation of a number of OFET techniques, including use of silanes or thiols, or OFET operation or aging. Techniques provide an internal circuit probe, such as for a ferroelectric gate dielectric OFET or a piezoelectric substrate OFET, for example.