Ferroelectric Solar Cell Charge Separation

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Solution Overview

Problem

Solar cells face charge injection and compounding losses, limiting their theoretical efficiency, and organic ferroelectric materials with good crystallinity and high remanent polarization are challenging to achieve, affecting charge transport and photoelectric conversion efficiency.

Innovation Solution

A ferroelectric enhanced solar cell structure incorporating a conductive substrate, hole blocking layer, mesoporous nanocrystalline layer, and mesoporous spacer layer with ferroelectric materials like BaSnO3 and CaTiO3, subjected to artificial polarization, to facilitate charge separation and transport without affecting insulating properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If organic ferroelectric materials are used to enhance photoelectric conversion efficiency, then charge separation is improved, but the insulating property of the material negatively affects charge transport inside the solar cells

Engineering Contradiction:
Improvecharge recombination lossVSAvoidcharge transport
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent employs composite material structures where ferroelectric materials are integrated with conductive materials. Specifically, ferroelectric perovskite layers are combined with conductive oxides or organic conductors to create a composite architecture that simultaneously achieves strong polarization for charge separation and adequate conductivity for charge transport. This composite approach resolves the contradiction by allowing each material to contribute its advantageous property.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies key parameters of the ferroelectric material including crystallinity enhancement, grain size optimization, and composition adjustment to balance polarization strength and charge transport. By controlling synthesis conditions to achieve higher crystallinity and optimizing the ferroelectric component ratio, the material exhibits improved remanent polarization while maintaining sufficient charge transport pathways.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If inorganic ferroelectric nanomaterials are used instead of organic ferroelectric materials, then remanent polarization is enhanced, but the insulating property may affect charge transport

Engineering Contradiction:
Improveremanent polarizationVSAvoidcharge transport
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent creates composite structures combining inorganic ferroelectric nanomaterials with conductive components. The inorganic ferroelectric phase provides high remanent polarization, while the conductive matrix or interface regions ensure efficient charge transport. This composite architecture allows the system to benefit from the high polarization of inorganic materials without suffering from their insulating characteristics.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements local quality optimization by creating regions with different properties within the solar cell structure. Ferroelectric nanomaterials are concentrated in specific layers or regions where high polarization is most beneficial for charge separation, while conductive pathways are engineered in adjacent or interfacial regions to facilitate charge transport. This spatial differentiation allows each region to optimize its function.

Inventive Principle:
Principle #3Local quality

3Productivity

If ferroelectric material is applied to facilitate charge transfer and transport, then photoelectric conversion efficiency is improved, but the insulating property of the material creates a trade-off with charge transport

Engineering Contradiction:
Improvephotoelectric conversion efficiencyVSAvoidcharge transport
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent utilizes composite material design where ferroelectric materials are integrated with conductive materials to create a synergistic structure. The ferroelectric component enhances photoelectric conversion through strong polarization effects, while the conductive component ensures efficient charge transport. This composite approach allows both functions to coexist and enhance each other.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces intermediary materials or interface structures that mediate between the ferroelectric material and the charge transport pathways. These intermediary layers or interface regions facilitate the transition of charges from the ferroelectric domain to the transport channels, reducing the negative impact of the insulating property while preserving the polarization benefit.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ferroelectric enhanced solar cell achieves improved photoelectric conversion efficiency by generating an oriented electric field, reducing recombination and transmission losses, and maintaining effective charge transport, as demonstrated in examples with increased efficiency under simulated sunlight.

Implementation Method 1

In the cell structure of the ferroelectric material, electric dipole moment occurs due to the misalignment of positive and negative charge centers, resulting in an electric polarization intensity not equal to zero, so that the material has spontaneous polarization. Under the action of an applied electric field, the direction of the electric dipole moment changes along the electric field, thereby generating an oriented electric field inside the material. This property of the material is called ferroelectricity.

Methodology Applied
Scientific EffectFerroelectricity:

Implementation Method 2

Solar cells directly convert solar energy to electricity

Methodology Applied
Scientific EffectPhotoelectric conversion: Photovoltaic Effect

Data Source

PatentEP3553830B1Ferroelectric-enhanced solar cell and preparation method therefor
Publication Date: 2023.08.09 HUAZHONG UNIV OF SCI & TECH
  • EP3553830B1 patent drawingFigure 1

AI summary

Disclosed by the present invention are a ferroelectric-enhanced solar cell and a preparation method therefor, wherein the ferroelectric-enhanced solar cell comprises a conductive substrate (1), and a hole barrier layer (2), a mesoporous nanocrystalline layer (3), a mesoporous separation layer (4), and a mesoporous back electrode layer (5) that are sequentially deposited on the conductive substrate (1); the mesopores of at least one from among the mesoporous nanocrystalline layer (3), the mesoporous separation layer (4) and the mesoporous back electrode layer (5) are filled with an optical active material; at least one from among the hole barrier layer (2), the mesoporous nanocrystalline layer (3) and the mesoporous separation layer (4) comprises a ferroelectric material or a ferroelectric nano-composite material. The present invention replaces an ordinary thin film by using a ferroelectric nano material having good crystallization, such as nano particles, such that residual polarization strength is higher, while not influencing the transmission of the carrier; furthermore, an inorganic ferroelectric material processed by means of a special manual polarization process may further effectively promote the separation and transmission of the carrier.