Ferromagnetic Sputtering Target with Dispersed Oxide Grains

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Solution Overview

Problem

Magnetron sputtering devices experience unstable electrical discharge and high particle generation when using ferromagnetic sputtering targets, leading to reduced pass-through flux and defective magnetic recording films in hard disk drives.

Innovation Solution

A ferromagnetic sputtering target with a nonmagnetic-grain-dispersed structure, where nonmagnetic oxide grains are dispersed in a metal matrix with specific composition and phase ratios, and metal phases having a component composition different from the basis metal, optimized to reduce particle generation and enhance pass-through flux.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a ferromagnetic sputtering target is used in a magnetron sputtering device, then the productivity for depositing magnetic recording films is improved, but the electrical discharge becomes unstable and particle generation increases

Engineering Contradiction:
Improvedeposition productivityVSAvoidelectrical discharge stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies local quality by creating a non-uniform magnetic flux distribution within the sputtering target. Specifically, it designs a composite structure where ferromagnetic alloy regions and nonmagnetic inorganic grain regions are spatially separated, causing magnetic flux to concentrate in the ferromagnetic regions and avoid the nonmagnetic regions. This local differentiation of magnetic properties stabilizes the electrical discharge while maintaining high deposition productivity.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by combining ferromagnetic alloy (such as Co-Cr-Pt) with nonmagnetic inorganic grains (such as oxide grains) to create a sputtering target with dual functionality. The ferromagnetic regions provide the necessary magnetic properties for efficient sputtering, while the nonmagnetic regions act as flux barriers that stabilize the discharge. This composite structure resolves the contradiction between productivity and discharge stability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If a ferromagnetic sputtering target is used in a magnetron sputtering device, then the productivity is improved, but the pass-through flux decreases and particle generation increases

Engineering Contradiction:
Improvedeposition productivityVSAvoidparticle generation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent applies the taking out principle by extracting the nonmagnetic inorganic grains from the continuous ferromagnetic matrix and distributing them as discrete phases throughout the target. These extracted nonmagnetic regions serve as flux barriers that prevent excessive magnetic flux penetration, thereby reducing particle generation while maintaining the overall ferromagnetic character needed for high productivity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The composite material structure combines ferromagnetic alloy with dispersed nonmagnetic inorganic grains. The nonmagnetic grains act as internal flux barriers that reduce the pass-through flux to optimal levels, preventing the formation of particles during sputtering. This composite approach allows simultaneous achievement of high productivity and low particle generation.

Inventive Principle:
Principle #40Composite materials

3Reliability

If nonmagnetic inorganic grains are dispersed in the ferromagnetic alloy, then the electrical discharge stability is improved, but the manufacturing complexity increases

Engineering Contradiction:
Improveelectrical discharge stabilityVSAvoidtarget structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by controlling the size, shape, and distribution of nonmagnetic inorganic grains within the ferromagnetic alloy matrix. By optimizing parameters such as grain size (typically 1-10 μm) and volume fraction (5-20%), the patent achieves stable electrical discharge without requiring complex multi-layer structures or intricate geometries, thus balancing discharge stability with manufacturing simplicity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The target achieves stable electrical discharge and improved pass-through flux, reducing particle generation and extending target life, while enabling the production of high-quality magnetic thin films at lower costs.

Implementation Method 1

a magnetron sputtering device comprising a DC power source

Methodology Applied
Scientific EffectMagnetic field: Magnetic Field

Implementation Method 2

inert gas is ionized, plasma composed of electrons and positive ions is formed

Methodology Applied
Scientific EffectIonization: Ionisation

Implementation Method 3

plasma composed of electrons and positive ions is formed

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 4

the positive ions in this plasma collide with the target (negative electrode) surface to discharge the constituent atoms of the target, and the extruded atoms adhere to the opposing substrate surface to form a film

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS9181617B2Sputtering target of ferromagnetic material with low generation of particles
Publication Date: 2015.11.10 JX NIPPON MINING & METALS CORP
  • US9181617B2 patent drawing
  • US9181617B2 patent drawing
  • US9181617B2 patent drawing

AI summary

Provided is a sputtering target of ferromagnetic material comprising a metal having a composition containing 20 mol % or less of Cr, and Co as the remainder; wherein the target structure includes a phase (A) which is a basis metal, and metal phases (B) having a component composition different from the peripheral texture within the phase (A), the area ratio occupied by oxides within 1 μm from the most outer periphery of metal phases (B) is 80% or less, and the average grain size of the metal phases (B) is 10 μm or more and 150 μm or less. Provided is a sputtering target of ferromagnetic material capable of inhibiting the generation of particles during sputtering, and improving the pass-through flux to achieve a stable electrical discharge with a magnetron sputtering device.