Fertilizer Core Particle with pH Buffering Agents

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Solution Overview

Problem

Continuous use of fertilizers leads to soil fertility decline and environmental issues like greenhouse emissions and groundwater contamination due to rapid hydrolysis and nitrification of urea, and existing solutions face challenges with thermal and pH sensitivity of inhibitors, requiring an improved fertilizer granule with enhanced application properties.

Innovation Solution

A fertilizer core particle comprising binders, pH buffering agents, and viscoelasticity agents, with a nitrogen-containing fertilizer composition, is developed, which is extruded to form a granule that stabilizes the active ingredients and controls nitrogen release, preventing degradation and improving soil pH balance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If urea is applied to increase crop yield, then nitrogen availability improves, but rapid hydrolysis and nitrification cause soil health deterioration and environmental pollution

Engineering Contradiction:
Improvenitrogen availabilityVSAvoidgreenhouse emissions and groundwater contamination
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent introduces pH buffering agents (such as calcium carbonate, magnesium oxide, or their mixtures) as intermediary substances that mediate between urea and the soil environment. These buffering agents maintain pH within 6.0-8.0, preventing the acidic conditions that trigger rapid nitrification and ammonia volatilization, thereby reducing greenhouse emissions and groundwater contamination while preserving nitrogen availability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the pH parameter of the fertilizer composition by incorporating pH buffering agents. By maintaining pH within the optimal range of 6.0-8.0, the composition modifies the chemical environment to slow down hydrolysis and nitrification rates, transforming the harmful rapid-release mechanism into a controlled-release process that reduces environmental pollution

Inventive Principle:
Principle #35Parameter changes

2Loss of substance

If inhibitors are added to control nitrification, then nitrogen loss is reduced, but thermal and pH sensitivity causes degradation of active ingredients

Engineering Contradiction:
Improvenitrogen lossVSAvoidstability of active ingredients
Core Design Contradiction:
Loss of substanceVSReliability

Solution Approach 1:

The patent creates a composite fertilizer composition containing multiple components: nitrogen fertilizer (urea), pH buffering agents (calcium carbonate, magnesium oxide), viscoelasticity agents (starch, cellulose derivatives), and fertilization modifiers. This composite structure protects sensitive active ingredients by maintaining stable pH and providing a protective matrix that reduces thermal degradation during granulation and application

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the thermal and pH parameters of the fertilizer system by incorporating buffering agents that resist pH changes and control the thermal environment during processing. This creates a more stable parameter environment that prevents degradation of temperature-sensitive and pH-sensitive active ingredients while still allowing nitrification inhibition to occur

Inventive Principle:
Principle #35Parameter changes

3Stability of the object's composition

If separate applications of micronutrient fertilizers and inhibitors are made, then soil fertility is improved, but application complexity and labor increase

Engineering Contradiction:
Improvesoil fertilityVSAvoidapplication process complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent merges multiple fertilizer components (nitrogen fertilizer, micronutrients, pH buffering agents, viscoelasticity agents, and fertilization modifiers) into a single composite granule formulation. This unified composition eliminates the need for separate applications of different fertilizer types and inhibitors, reducing application complexity and labor while maintaining improved soil fertility and crop yield

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively stabilizes fertilizer additives, reduces nitrogen loss, and maintains soil pH, enhancing crop yield while minimizing environmental impact by controlled nitrogen release and improved soil health.

Implementation Method 1

a method preparing a fertilizer core particle disclosed herein comprising the step of: a) extruding a mixture comprising one or more fertilizer additives, one or more binders, and one or more pH buffering agents

Methodology Applied
Scientific EffectExtrusion: Extrusion

Implementation Method 2

fertilizer core particle having an outer surface and comprising one or more fertilizer additives, one or more binders, and one or more pH buffering agents

Methodology Applied
Scientific EffectBinding: Binder

Implementation Method 3

one or more pH buffering agents, and wherein the fertilizer core particle comprises from about 10 wt % to about 99 wt % of the one or more binders

Methodology Applied
Scientific EffectpH buffering:

Implementation Method 4

b) granulating the core particle with a nitrogen containing fertilizer composition, thereby forming a fertilizer granule

Methodology Applied
Scientific EffectGranulation:

Data Source

PatentUS11104618B2Fertilizer composition and methods of making and using same
Publication Date: 2021.08.31 SABIC AGRI NUTRIENTS CO
  • US11104618B2 patent drawing
  • US11104618B2 patent drawing
  • US11104618B2 patent drawing

AI summary

In accordance with the present invention, disclosed herein is a fertilizer core and fertilizer granule and methods related thereto. The fertilizer core particle has an outer surface and comprising one or more fertilizer additives, one or more binders, and one or more pH buffering agents, and wherein the fertilizer core particle comprises from about 10 wt % to about 99 wt % of the one or more binders.