FFS Liquid Crystal Display Polymer Blocking Layer

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Solution Overview

Problem

Liquid crystal displays (LCDs) with negative dielectric anisotropy in the Fringe Field Switching (FFS) mode face issues such as low reliability, high viscosity, and image sticking due to interactions between LC molecules and the polyimide alignment layer, leading to reduced voltage holding ratio (VHR) and increased sensitivity to UV exposure.

Innovation Solution

Incorporating di- or multireactive polymerizable compounds with acrylate and methacrylate groups into the LC medium, which induces planar alignment and forms a crosslinked polymer upon polymerization, creating a blocking layer that prevents ion extraction from the polyimide layer and enhances VHR, especially after UV exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If LC medium with negative dielectric anisotropy is used in FFS display, then transmission is improved and viewing angle dependence is reduced, but reliability deteriorates due to ion extraction from polyimide alignment layer

Engineering Contradiction:
ImprovetransmissionVSAvoidvoltage holding ratio
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

A polymerizable compound is introduced as an intermediary substance between the LC medium and polyimide alignment layer. This compound forms a blocking layer through polymerization that mediates the interaction between LC molecules and polyimide, preventing ion extraction while maintaining the beneficial planar alignment and transmission properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The LC medium is formulated as a composite material containing both the base LC compound and a polymerizable compound. This composite structure combines the high transmission and viewing angle properties of negative dielectric anisotropy LC media with the protective blocking layer formed by the polymerizable compound, resolving the reliability issue.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If polyimide alignment layer is used, then planar alignment is achieved, but ion extraction occurs leading to image sticking and reduced VHR

Engineering Contradiction:
Improveplanar alignmentVSAvoidion extraction
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The polymerizable compound acts as an intermediary layer between the polyimide alignment layer and LC medium. It maintains the planar alignment function of polyimide while blocking the harmful ion extraction process, thus preserving alignment performance without the harmful side effects.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The polymerizable compound utilizes UV exposure, which normally causes degradation and ion extraction, and converts this harmful effect into a beneficial blocking layer formation. The UV-induced polymerization creates a protective barrier that prevents further ion extraction and improves long-term reliability.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If UV exposure is applied, then polymerization occurs improving VHR, but degradation reactions produce ionic impurities

Engineering Contradiction:
Improvevoltage holding ratioVSAvoidionic impurities
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The introduction of the polymerizable compound changes the chemical parameters of the LC medium system. This new component provides a controlled polymerization pathway that outcompetes degradation reactions, converting UV energy into beneficial crosslinking rather than harmful decomposition, thus improving VHR without significant ionic impurity formation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of di- or multireactive polymerizable compounds in the LC medium improves the reliability and VHR of FFS displays, reducing image sticking and maintaining high performance across a broad temperature range with reduced rotational viscosity and faster switching times.

Implementation Method 1

the polymerizable compounds are polymerized in the display, in particular by irradiation with UV light

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

the LC medium usually has a negative value of the dielectric (DC) anisotropy

Methodology Applied
Scientific EffectDielectric anisotropy: Dielectric Permittivity

Implementation Method 3

an alignment layer provided on at least one of the substrates that is in contact with the LC medium and induces planar alignment of the LC molecules

Methodology Applied
Scientific EffectSurface alignment: Adsorption

Data Source

PatentEP2896678B1Liquid crystal display
Publication Date: 2018.10.17 MERCK PATENT GMBH
  • EP2896678B1 patent drawing
  • EP2896678B1 patent drawing
  • EP2896678B1 patent drawing

AI summary

The present invention relates to a liquid crystal (LC) display of the FFS type comprising a liquid crystal medium with negative dielectric anisotropy and a di- or multireactive polymerisable compound, and an alignment layer inducing planar alignment in the LC medium.