Fiber Optic CO2 Purity Sensor With Isothermal Gas Chamber

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Solution Overview

Problem

Existing carbon dioxide (CO2) purity detection methods face challenges such as thermal drifting issues in thermal conductivity detection, limitations in measuring CO2 purity when blended with hydrocarbon gases, and accuracy degradation due to variations in light absorption caused by temperature, pressure, and density changes.

Innovation Solution

A fiber optic CO2 purity sensor package with a periodic refractive index modulated fiber grating structure, a thermally conductive sensing layer, and a thermally insulated gas chamber, which maintains the sensor in an isothermal state and uses a light source, photodetector, and processing circuitry to analyze reflected optical signals for accurate CO2 purity measurement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If thermal conductivity detection (TCD) is used for CO2 purity detection, then general-purpose gas analysis capability is provided, but thermal drifting issues occur resulting in low measurement precision

Engineering Contradiction:
Improvegeneral-purpose gas analysis capabilityVSAvoidCO2 gas purity analysis resolution
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

The patent replaces thermal conductivity detection (TCD) with optical detection using a fiber Bragg grating (FBG) sensor system. The FBG sensor detects CO2 purity through optical wavelength shifts caused by thermal expansion and refractive index changes in the grating structure, eliminating the thermal drifting issues inherent in TCD mechanical/thermal systems while maintaining general-purpose gas analysis capability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the detection parameter from thermal conductivity to optical wavelength. The FBG sensor measures CO2 purity by detecting wavelength shifts (Δλ) that occur in response to temperature and strain changes induced by CO2 absorption, providing high measurement precision without the thermal drift problems of TCD

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If NDIR optical detection is used for CO2 purity measurement, then optical detection capability is provided, but measurement accuracy degrades when CO2 is blended with hydrocarbon gases

Engineering Contradiction:
ImproveCO2 purity measurement capabilityVSAvoidmeasurement accuracy with hydrocarbon blends
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by using a fiber Bragg grating structure with specific localized modifications - the grating period and refractive index are modified in specific regions of the fiber to create sensitivity to CO2 while being insensitive to hydrocarbon interference. The sensing zone is locally optimized for CO2 detection through controlled thermal and optical properties

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces an intermediary mechanism - the fiber Bragg grating structure acts as a mediator that converts CO2 concentration changes into optical wavelength shifts. This intermediary transformation process eliminates the direct optical absorption measurement limitations of NDIR when dealing with hydrocarbon blends, as the FBG responds to thermal-structural changes rather than direct gas absorption

Inventive Principle:
Principle #24Intermediary (Mediator)

3Measurement precision

If fluorescence detection with dye embedded polymeric thin film is used, then optical CO2 purity monitoring is provided, but baseline drift and accuracy degradation occur due to variations in light absorption from temperature, pressure, and density changes

Engineering Contradiction:
ImproveCO2 gas purity monitoring accuracyVSAvoidbaseline stability under temperature and pressure variations
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The patent replaces the fluorescence detection system with an FBG optical sensing system. Instead of using dye molecules that emit fluorescence and are susceptible to environmental variations, the FBG sensor uses the physical structure of the fiber grating itself, which provides inherent stability against temperature and pressure changes through its solid-state, distributed sensing mechanism

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The fiber Bragg grating sensor is self-compensating for temperature and pressure effects. The FBG wavelength shift naturally accounts for environmental variations, and the system uses the fiber's own structural properties to maintain baseline stability without requiring external reference measurements or complex compensation algorithms

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides high sensitivity and accuracy in measuring CO2 purity across a wide range, effectively addressing baseline drift and temperature variations, enabling reliable detection in various industrial applications.

Implementation Method 1

a periodic refractive index modulated fiber grating structure within the fiber core

Methodology Applied
Scientific EffectBragg Diffraction: Bragg Diffraction

Implementation Method 2

a thermally conductive sensing layer positioned about a portion of the fiber cladding surrounding the periodic refractive index modulated fiber grating structure

Methodology Applied
Scientific EffectThermal Conduction: Conduction (thermal)

Implementation Method 3

a thermally insulated cylindrical gas chamber for maintaining the CO2 purity sensor in an isothermal state

Methodology Applied
Scientific EffectThermal Insulation: Thermal Insulation

Data Source

PatentUS8467977B2Fiber optic carbon dioxide purity sensor package and system
Publication Date: 2013.06.18 GE INFRASTRUCTURE TECH LLC
  • US8467977B2 patent drawing
  • US8467977B2 patent drawing
  • US8467977B2 patent drawing

AI summary

A carbon dioxide (CO2) purity sensor package includes a fiber core, a periodic refractive index modulated fiber grating structure within the fiber core and a fiber cladding. A thermally conductive sensing layer is positioned about a portion of the fiber cladding surrounding the periodic refractive index modulated fiber grating structure. A gas chamber encloses the fiber cladding with the thermally conductive sensing layer.