Fiber-Based Porous Electrodes for High-Cyclability Power Storage

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Solution Overview

Problem

Conventional electrical power storage devices, such as batteries and capacitors, face limitations in power storage capacity, weight, and cyclability due to structural integrity and porosity issues, leading to underutilization of active material and increased risk of electrode degradation.

Innovation Solution

The use of high surface area fibers in electrodes for power storage devices, which enhance permeability and structural integrity while reducing the amount of active material required, allowing for simultaneous energy storage as both electrochemical batteries and capacitors, thereby improving power-to-size ratio.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional lead-acid battery electrodes use lead paste applied to a substrate with limited porosity, then the electrode maintains structural integrity, but a significant amount of active material is inaccessible to the electrolyte and is underutilized

Engineering Contradiction:
Improvestructural integrityVSAvoidactive material utilization
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies porous materials by incorporating a porous polymer foam substrate as the electrode base structure. This foam substrate provides high porosity (typically 70-90% void volume) that allows electrolyte penetration throughout the electrode, making nearly all active material accessible. The porous structure is achieved through controlled foaming processes that create interconnected cellular structures, resolving the contradiction between structural integrity and active material utilization by providing both mechanical support and electrolyte access.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses composite materials by combining the porous polymer foam substrate with lead paste or other active materials to create a composite electrode structure. The foam substrate provides structural integrity and porosity, while the active material coating provides electrochemical functionality. This composite approach allows the electrode to simultaneously maintain structural strength and achieve high active material utilization through the foam's porous network.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional electrodes increase porosity to improve electrolyte access, then active material utilization increases, but the electrode's structural integrity deteriorates

Engineering Contradiction:
Improveactive material utilizationVSAvoidstructural integrity
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The porous polymer foam substrate inherently provides high porosity (70-90% void volume) while maintaining structural integrity through its three-dimensional cellular network. The foam structure's cell walls and interconnected pores provide both electrolyte access and mechanical strength, eliminating the need to compromise structural integrity to achieve high porosity. The foam's inherent porous architecture simultaneously delivers both high active material utilization and structural strength.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies parameter changes by utilizing the foam substrate's controllable porosity parameters (cell size, cell wall thickness, void fraction) to optimize both structural integrity and electrolyte access. By adjusting foam manufacturing parameters such as blowing agent concentration, curing conditions, and cell structure characteristics, the electrode can be tailored to achieve specific porosity levels that maximize active material utilization while maintaining adequate mechanical strength for the application.

Inventive Principle:
Principle #35Parameter changes

3Loss of energy

If conventional capacitors use thick conductive plates to reduce resistance loss, then resistance decreases, but the capacitor's power storage to weight ratio is limited

Engineering Contradiction:
Improveresistance lossVSAvoidpower storage to weight ratio
Core Design Contradiction:
Loss of energyVSWeight of moving object

Solution Approach 1:

The patent applies porous materials by using porous polymer foam electrodes instead of conventional solid plates. The foam's high surface area to volume ratio and three-dimensional porous network provide extensive electrochemically active surface area while maintaining electrical conductivity through the conductive polymer matrix and embedded conductive additives. This porous structure enables high capacitance (energy storage) with minimal material mass, dramatically improving the power storage to weight ratio while the interconnected conductive network keeps resistance losses low.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies dimensionality change by transitioning from two-dimensional plate structures to three-dimensional porous foam structures. The foam's three-dimensional network of interconnected pores and conductive pathways provides electrical conduction in multiple dimensions, reducing current path length and resistance compared to conventional thick plates. Simultaneously, the 3D structure maximizes surface area for charge storage without increasing mass proportionally, improving the power storage to weight ratio.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Quantity of substance

If conventional capacitors decrease plate separation to increase energy storage, then capacitance increases, but the risk of charge passing directly between plates (short circuit) increases

Engineering Contradiction:
Improveenergy storage capacityVSAvoidshort circuit risk
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies porous materials by using porous polymer foam as both the electrode substrate and the separator structure. The foam's three-dimensional cellular structure with controlled pore sizes (typically micrometer to millimeter scale) provides physical separation between positive and negative electrodes while allowing ionic transport through the pores. The interconnected pore network and cell wall structure prevent direct electrical contact between electrodes even at close spacing, eliminating short circuit risk while enabling high capacitance through the large surface area and reduced inter-electrode distance.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies the intermediary principle by using the porous foam structure as a mediating separator between electrodes. The foam's porous matrix acts as an intermediary that allows ionic current to pass through its pores while its solid cell walls and structural framework prevent electronic current (short circuits) from passing directly between electrodes. This intermediary structure enables close electrode spacing for high energy storage while maintaining electrical isolation for safety.

Inventive Principle:
Principle #24Intermediary (Mediator)

5Power

If conventional electrodes undergo repeated charge-discharge cycles, then power delivery increases, but the electrode degrades and sections become electrically disconnected

Engineering Contradiction:
Improvepower deliveryVSAvoidcyclability
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent applies porous materials by using porous polymer foam substrate that provides a flexible, resilient structure capable of withstanding repeated expansion and contraction during charge-discharge cycles. The foam's cellular structure can accommodate volume changes of the active material without fracturing or losing structural integrity, preventing electrode degradation and electrical disconnection. The porous network maintains electrolyte access and ionic pathways even after extensive cycling, preserving both power delivery and cyclability.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent uses composite materials by combining the porous foam substrate with active materials in a composite electrode structure that enhances cyclability. The foam substrate provides mechanical flexibility and structural stability that prevents degradation during cycling, while the active material coating provides electrochemical functionality. This composite structure maintains electrical connectivity and structural integrity over thousands of cycles, enabling sustained high power delivery with improved reliability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The incorporation of high surface area fibers increases the effective surface area and conductivity of electrodes, leading to improved charge retention, reduced material usage, and enhanced cyclability, resulting in more efficient and durable power storage devices.

Implementation Method 1

the at least one of the at least one negative electrode or at least one positive electrode includes high surface area fibers

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

Both the separator and electrodes arc infused with an electrolytic solution. This allows ionic current to flow between the electrodes through the separator, but prevents electrical current from shorting the cell.

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentUS11764363B2Electrical power storage devices
Publication Date: 2023.09.19 CPS TECHNOLOGY HOLDINGS LLC
  • US11764363B2 patent drawing
  • US11764363B2 patent drawing
  • US11764363B2 patent drawing

AI summary

An electrical storage device includes high surface area fibers (e.g., shaped fibers and/or microfibers) coated with carbon (graphite, expanded graphite, activated carbon, carbon black, carbon nanofibers, CNT, or graphite coated CNT), electrolyte, and/or electrode active material (e.g., lead oxide) in electrodes. The electrodes are used to form electrical storage devices such as electrochemical batteries, electrochemical double layer capacitors, and asymmetrical capacitors.