Fiber-treating agent

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Solution Overview

Problem

Regenerated collagen fibers used in hair ornament products face issues with high water absorption leading to mechanical strength deterioration, low heat resistance, and lack of heat shape memory ability, limiting their popularity compared to synthetic fibers.

Innovation Solution

A fiber-treating agent comprising a compound with a methylol group bonded to two nitrogen atoms and a phenolic compound with specific electron donating groups, applied to naturally derived fibers to enhance water resistance, heat resistance, and impart heat shape memory ability, while improving stretchability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If regenerated collagen fibers are used for hair ornament products, then natural texture and appearance are achieved, but mechanical strength significantly decreases when water absorption is high

Engineering Contradiction:
Improvenatural texture and appearanceVSAvoidmechanical strength
Core Design Contradiction:
Illumination intensityVSStrength

Solution Approach 1:

A crosslinking agent is introduced as an intermediary substance that forms crosslinks between collagen molecules. This mediator creates a three-dimensional network structure that reinforces the fiber, maintaining mechanical strength while preserving the natural appearance and texture of the regenerated collagen fibers.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite structure by combining regenerated collagen fibers with crosslinked networks. The crosslinked collagen complex forms a reinforced composite material that integrates the natural properties of collagen with the structural strength of the crosslinked network, solving the contradiction between natural appearance and mechanical strength.

Inventive Principle:
Principle #40Composite materials

2Reliability

If regenerated collagen fibers absorb water, then hydrophilicity is maintained, but mechanical strength deteriorates

Engineering Contradiction:
ImprovehydrophilicityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

Crosslinking is performed preliminarily during the fiber formation process, before the fibers are subjected to wet conditions. This preliminary crosslinking creates a pre-reinforced structure that prevents water from disrupting the molecular arrangement, allowing the fibers to maintain both hydrophilicity and mechanical strength when exposed to water during subsequent use.

Inventive Principle:
Principle #10Preliminary action

3Temperature

If high temperature is applied to regenerated collagen fibers, then heat styling is achieved, but shrinkage or crimping occurs

Engineering Contradiction:
Improveheat styling capabilityVSAvoidshape stability
Core Design Contradiction:
TemperatureVSShape

Solution Approach 1:

The crosslinked network acts as a structural intermediary that stabilizes the collagen fiber architecture during thermal processing. This crosslinked framework serves as a thermal buffer, allowing the fibers to withstand high temperatures required for heat styling without undergoing unwanted shrinkage or crimping, thereby maintaining shape stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Shape

If regenerated collagen fibers are heat set, then temporary shape is achieved, but shape memory is lost through subsequent washing

Engineering Contradiction:
Improveheat set shapeVSAvoidshape memory
Core Design Contradiction:
ShapeVSStability of the object's composition

Solution Approach 1:

Crosslinking is performed preliminarily to establish a stable three-dimensional network structure that can permanently retain the heat-set shape. This pre-formed crosslinked framework acts as a memory scaffold, allowing the fibers to maintain the desired shape even after subsequent washing, thereby achieving permanent shape memory capability.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The treatment significantly improves the water resistance, heat resistance, and stretchability of naturally derived fibers, allowing them to maintain shape sustainability and durability, comparable to human hair, and provides heat shape memory ability.

Implementation Method 1

a method is known in which a compound having a methylol group is applied

Methodology Applied
Scientific EffectCondensation reaction:

Implementation Method 2

to modify regenerated collagen fibers to impart water resistance and heat resistance, an attempt has been made to apply a reactive substance to amino groups of a collagen molecule

Methodology Applied
Scientific EffectCrosslinking:

Implementation Method 3

immersing fibers in the fiber-treating agent

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS20240049824A1Fiber-treating agent
Publication Date: 2024.02.15 KAO CORP
  • US20240049824A1 patent drawing
  • US20240049824A1 patent drawing
  • US20240049824A1 patent drawing

AI summary

A fiber-treating agent, where the fiber-treating agent is a one part fiber-treating agent including a single composition or a multiple-part fiber-treating agent including a plurality of compositions. The fiber-treating agent contains the following components (A) to (C) in a total composition thereof, and where, for the one-part fiber-treating agent, a part or all of the components (A) and (B) is optionally a condensate formed from the components: (A): a compound having a structure wherein a methylol group is bonded to each of two nitrogen atoms in the compound, (B): a phenolic compound having an electron donating group on at least one of meta-positions and a hydrogen atom on at least one of ortho-positions and a para-position, wherein the electron donating group on the meta-position optionally forms, together with adjacent carbon atoms, a benzene ring optionally substituted with a hydroxy group, and (C): water.