Fibril Structuring Agents for Liquid Fertilizer Agrochemical Compatibility

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Solution Overview

Problem

Existing agrochemical formulations face stability and efficacy issues when mixed with liquid fertilizers, particularly high-phosphate starter fertilizers, due to compatibility problems such as phase separation, flocculation, and clogging of application equipment, which affect uniform application and biological performance.

Innovation Solution

A composition comprising a fibril, microfibril, or nanofibril structuring agent, such as microfibrillated cellulose, combined with agriculturally bioactive materials like fungicides, insecticides, and herbicides, which improves dispersibility and compatibility with liquid fertilizers, preventing clogging and ensuring uniform application.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If traditional compositions containing surface active agents, viscosity modifiers, wetting agents, and antifreeze are used, then the formulation can be prepared, but non-uniform dispersion occurs resulting in residue on application filters and non-uniform application

Engineering Contradiction:
Improveuniformity of dispersionVSAvoidapplication uniformity
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent changes the physical-chemical parameters of the formulation by incorporating polysaccharide derivatives and specific surfactants in controlled concentrations, adjusting viscosity and surface tension properties to achieve uniform dispersion in liquid fertilizer solutions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses polysaccharide derivatives and surfactants as intermediary substances that mediate between the bioactive material and liquid fertilizer, preventing direct incompatibility and enabling uniform mixing without residue formation on filters

Inventive Principle:
Principle #24Intermediary (Mediator)

2Stability of the object's composition

If dilution of formulation in water before adding to liquid fertilizer is used, then compatibility issues can be mitigated, but an additional preparation step is required and area covered per application load is reduced

Engineering Contradiction:
Improvecompatibility with liquid fertilizerVSAvoidarea covered per application load
Core Design Contradiction:
Stability of the object's compositionVSProductivity

Solution Approach 1:

The patent performs preliminary formulation work by pre-mixing the bioactive material with compatible carriers and adjuvants in a stable emulsion or suspension that can be directly applied to liquid fertilizer without requiring on-site dilution, thus maintaining compatibility while eliminating the additional preparation step

Inventive Principle:
Principle #10Preliminary action

3Duration of action of moving object

If xanthan gum is used as a thickener, then rheological properties are controlled with shear thinning characteristics, but phase separation and flocculation occur when mixed with high-phosphate starter fertilizer

Engineering Contradiction:
Improverheological controlVSAvoidphase stability
Core Design Contradiction:
Duration of action of moving objectVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters by replacing xanthan gum with alternative polysaccharide derivatives that have different molecular structures and interaction properties, maintaining desired rheological characteristics while eliminating phase separation and flocculation with high-phosphate fertilizers

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite thickening system combining multiple polysaccharide derivatives with different functional properties, where the composite material achieves both rheological control and chemical compatibility with high-phosphate fertilizers that neither component could achieve alone

Inventive Principle:
Principle #40Composite materials

4Stability of the object's composition

If silica or clay-based thickeners are used, then compatibility with high-phosphate fertilizer is improved, but robustness and versatility during scale-up are reduced

Engineering Contradiction:
Improvecompatibility with high-phosphate fertilizerVSAvoidscale-up robustness
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The patent changes the molecular weight, degree of polymerization, and chemical structure parameters of the polysaccharide derivatives to optimize both fertilizer compatibility and formulation robustness across different scales, achieving properties that bridge the gap between laboratory success and industrial scalability

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of fibril or microfibril structuring agents enhances the stability and uniformity of agrochemical formulations in liquid fertilizers, reducing sedimentation and improving flowability, thereby maintaining the physical stability and biological effectiveness of the bioactive materials during application.

Implementation Method 1

a composition in combination with a fibril, microfibril, or nanofibril structuring agent... readily dispersible in liquid fertilizers

Methodology Applied
Scientific EffectDispersion: Dispersion (of waves)

Implementation Method 2

enhances the stability and uniformity of agrochemical formulations in liquid fertilizers, reducing sedimentation

Methodology Applied
Scientific EffectSedimentation resistance: Sedimentation

Implementation Method 3

improving flowability, thereby maintaining the physical stability and biological effectiveness of the bioactive materials during application

Methodology Applied
Scientific EffectFlowability enhancement:

Data Source

PatentUS11849724B2Liquid fertilizer-dispersible compositions and methods thereof
Publication Date: 2023.12.26 BAYER CROPSCIENCE LP
  • US11849724B2 patent drawing
  • US11849724B2 patent drawing
  • US11849724B2 patent drawing

AI summary

The present disclosure relates to the field of agrochemical compositions and formulations. In an aspect, the present disclosure provides for a composition in combination with a fibril or microfibril or nanofibril structuring agent. In yet another aspect, the disclosure provides for a composition comprising: (a) an agricultural bioactive material, a fungicide, insecticide, herbicide, and/or plant growth regulator; (b) a fibril or microfibril or nanofibril structuring agent; and (c) optionally, an auxiliary surface active agent. The disclosure further provides for a comprising a composition described herein mixed or combined with a liquid fertilizer.