Fibrillated Nanofiber Filter for Colloidal Lead Removal

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Solution Overview

Problem

Existing water treatment technologies face challenges in effectively removing soluble and insoluble lead, particularly at high pH levels, as they struggle to meet stringent standards for lead reduction in drinking water, such as NSF/ANSI 53, especially for colloidal lead particles that are difficult to filter due to their size and stability in high pH environments.

Innovation Solution

The use of fibrillated nanofibers as filter media, combined with ion exchange beads, resins, or powders, creates a physical barrier to capture colloidal lead particles, allowing them to transform into soluble form and be removed by a secondary filter media, enhancing filtration efficiency and meeting the NSF standards for lead reduction in both low and high pH conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional filter media are used to remove colloidal lead particles, then filtration is attempted, but the filter media cannot effectively capture colloidal particles due to their small size and stability in high pH environments

Engineering Contradiction:
Improvelead removal effectivenessVSAvoidcolloidal particle stability
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite filter media consisting of fibrillated nanofibers combined with ion exchange resins. The fibrillated nanofibers provide a physical barrier structure with high surface area, while the ion exchange resins chemically interact with lead particles. This composite structure enables effective capture of colloidal lead particles that conventional single-material filters cannot remove, achieving lead reduction below 10 ppb in high pH conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The fibrillated nanofibers form a porous three-dimensional network structure with controlled pore sizes that allow selective passage of different particle sizes. The porous structure provides both physical filtration of colloidal particles and chemical interaction sites through the ion exchange resins embedded within the fibrillated matrix, enabling effective lead removal while maintaining fluid flow.

Inventive Principle:
Principle #31Porous materials

2Reliability

If a fine mesh filter is used to physically remove colloidal particles, then particle removal is improved, but the differential pressure increases and flow is restricted

Engineering Contradiction:
Improveparticle removal efficiencyVSAvoidfluid flow rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The fibrillated nanofibers create a porous three-dimensional network with hierarchical pore structures that provide high surface area for particle capture while maintaining open flow paths. The porous structure allows colloidal particles to be captured through adsorption and physical barrier mechanisms without creating a dense blocking layer, thus maintaining high fluid flow rates and low differential pressure drops.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The filter media exhibits local quality differentiation where the fibrillated nanofiber network provides physical barrier properties in certain regions while ion exchange resin zones provide chemical interaction properties in other regions. This spatial differentiation of functional properties allows efficient particle removal without requiring uniformly fine mesh throughout the entire filter media, thereby maintaining flow capacity.

Inventive Principle:
Principle #3Local quality

3Reliability

If ion exchange resins are used to remove soluble lead, then soluble lead removal is effective, but insoluble and colloidal lead particles pass through unchanged

Engineering Contradiction:
Improvesoluble lead removalVSAvoidparticle size range coverage
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent combines fibrillated nanofibers with ion exchange resins in a composite filter media where the fibrillated nanofibers provide physical barrier and adsorption properties for colloidal and insoluble particles, while the ion exchange resins provide chemical exchange properties for soluble lead. This composite structure enables simultaneous removal of lead in all three forms (soluble, colloidal, insoluble) across the entire particle size range.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The fibrillated nanofiber-based filter media performs multiple functions simultaneously: physical filtration of particles, adsorption of colloidal materials, and chemical ion exchange for soluble lead removal. This multi-functionality allows a single filter media to address the complete spectrum of lead contamination forms, making the system universally effective for comprehensive lead removal.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The implementation of fibrillated nanofibers in a filter system significantly improves the removal of colloidal lead particles, achieving lead reduction below 10 ppb, meeting or exceeding NSF standards, and maintaining hydraulic properties, even at high pH levels, thereby ensuring safe drinking water.

Implementation Method 1

the first and second filter media create a physical barrier for the colloidal material at their interface for capturing the colloidal particles

Methodology Applied
Scientific EffectFiltration: Filter (physical)

Implementation Method 2

a first filter media for filtering soluble material from the fluid; a second filter media, adjacent and in fluid communication with, the first filter media, for filtering the soluble material from the fluid

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 3

the colloidal particles retained at the interface until becoming soluble in the fluid, passing through the interface

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS8002990B2Uses of fibrillated nanofibers and the removal of soluble, colloidal, and insoluble particles from a fluid
Publication Date: 2011.08.23 KX TECHNOLOGIES LLC
  • US8002990B2 patent drawing
  • US8002990B2 patent drawing
  • US8002990B2 patent drawing

AI summary

A filter for removing soluble, colloidal, and insoluble particles from a fluid, including lead using a first filter media for filtering soluble material from the fluid, a second filter media, adjacent and in fluid communication with, the first filter media, for filtering soluble material from said fluid, wherein the first and second filter media create a physical non-soluble particle barrier at their interface for capturing non-soluble particles, that when retained at the interface, become soluble over time in the fluid, and are subsequently removed by the second filter media. At least one of the filter media can be fibrillated nanofibers that are loaded with finely subdivided media of powdered ion exchange resins. A third filter media may be placed between the first and second filter media to enhance capturing and dissolving the physical non-soluble particles.