Fibrous Substrate with In Situ Solid Hypochlorite Precipitate

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Solution Overview

Problem

Existing hypohalite-based disinfectant substrates face stability issues due to decomposition during storage and packaging, leading to reduced efficacy over time, especially in pre-wetted wipes and dry substrates with uneven distribution and slow release rates of hypochlorite, which are exacerbated by the use of binders and large particle sizes.

Innovation Solution

A process forming a solid hypochlorite precipitate on a fibrous substrate by exposing it to an aqueous alkaline earth salt solution and treating it with a hypohalite solution, allowing the precipitate to form around the fibers, resulting in a substrate that is substantially free of binders and adhesives, with the hypochlorite evenly distributed throughout, enabling rapid release upon moisture exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hypohalite solution is loaded onto an absorbent substrate to create pre-wetted wipes, then the substrate can provide disinfection capability, but the substrate lacks stability and decomposes during storage leading to reduced efficacy

Engineering Contradiction:
Improvedisinfection efficacyVSAvoidsubstrate stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the physical state of the hypohalite from liquid (in solution) to solid (precipitate), which fundamentally alters the stability characteristics. The solid precipitate form remains stable during storage while still providing disinfection efficacy when activated by moisture during use.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transition of the hypohalite from liquid phase (in solution) to solid phase (precipitate). This phase change enables the substrate to maintain stability during storage while retaining the ability to release active hypohalite when exposed to moisture during use.

Inventive Principle:
Principle #36Phase transitions

2Reliability

If solid hypohalite particles are adhered to the substrate surface, then the substrate can provide disinfection capability, but the particles are unevenly distributed and release slowly

Engineering Contradiction:
Improvedisinfection capabilityVSAvoidrelease rate
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges the hypohalite precipitate with the substrate structure itself, forming an integrated composite where the precipitate is distributed throughout the substrate matrix rather than merely adhered to the surface. This integration ensures uniform distribution and rapid, consistent release.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent utilizes the porous structure of the fibrous substrate to distribute and hold the solid hypohalite precipitate uniformly throughout the material. The porous network allows for even dispersion of particles and rapid capillary wicking of moisture to the active sites, enabling fast release.

Inventive Principle:
Principle #31Porous materials

3Strength

If binders or adhesives are used to attach hypohalite particles to the substrate, then the particles can be retained on the substrate, but the binders interfere with the quick release of hypochlorite

Engineering Contradiction:
Improveparticle retentionVSAvoidrelease speed
Core Design Contradiction:
StrengthVSSpeed

Solution Approach 1:

The patent removes and eliminates the binder or adhesive component from the system entirely. Instead of using binders to attach hypohalite particles, the invention uses the fibrous substrate structure itself and the formation of solid precipitate to retain and release the active material without any interfering binder substances.

Inventive Principle:
Principle #2Taking out (Extraction)

4Ease of operation

If large particle sizes are used for solid hypochlorite, then the particles can be easily handled and applied, but the release rate becomes too slow

Engineering Contradiction:
Improvehandling easeVSAvoidrelease rate
Core Design Contradiction:
Ease of operationVSSpeed

Solution Approach 1:

The patent changes the particle size parameter to an optimal range that balances handling ease with rapid release. The solid hypochlorite precipitate is formed as fine particles that can be easily incorporated into the substrate while maintaining sufficient surface area for rapid dissolution and release when activated by moisture.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting hypohalite-releasing substrate maintains effective disinfection capabilities for an extended period, ensuring rapid and uniform hypochlorite release without the need for sealable containers or binders, enhancing stability and performance compared to prior art.

Implementation Method 1

allowing the alkaline earth salt solution to react with the hypohalite solution to form solid hypochlorite precipitate around the fibers in the fibrous material

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

capable of rapid release of hypochlorite upon exposure to moisture or liquid

Methodology Applied
Scientific EffectDissolution:

Data Source

PatentUS8309508B2Fibrous substrate with a solid hypohalite precipitate formed therein
Publication Date: 2012.11.13 THE CLOROX CO

AI summary

A cleaning substrate which comprises at least one layer of a solid hypohalite precipitate, wherein the hypohalite precipitate is formed in situ on the layer of substrate material. A process for making a fibrous cleaning substrate comprising the steps of: a) providing at least one layer of fibrous material; b) exposing the fibrous layer to an aqueous alkaline earth salt solution; c) treating the fibrous layer with a hypochlorite solution; d) allowing the aqueous alkaline earth salt solution combine with the hypochlorite solution to form a solid hypochlorite precipitate around the fibers in the fibrous material and a liquid phase, and e) removing at least 65% of the liquid phase from the fibrous substrate.