Filled Epoxy Tubesheet Bending Under Thermal Stress

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Solution Overview

Problem

Air Separation Modules (ASMs) experience tubesheet cracking due to thermal cycles, leading to leakage and reduced separation selectivity, as existing tubesheets are brittle and prone to cracking under stress and temperature fluctuations.

Innovation Solution

The use of filled epoxy tubesheets, specifically aluminum-filled epoxy, which allows for bending under stress instead of cracking, incorporating a polymer component and a fill component to provide flexibility and minimize creep, with methods involving preheating resin and hardener for improved potting and adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional tubesheets are used in ASMs, then the structure provides initial stability, but the tubesheets crack under thermal cycling stress

Engineering Contradiction:
Improvetubesheet integrityVSAvoidresistance to thermal stress
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a composite material consisting of epoxy resin combined with aluminum flake filler. This composite provides both the adhesive bonding properties of epoxy and the thermal conductivity and flexibility of aluminum, allowing the tubesheet to withstand thermal cycling without cracking while maintaining structural integrity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the material parameters of the tubesheet by incorporating aluminum flake filler at specific concentrations (typically 20-40% by weight) and controlling the particle size distribution. This changes the thermal and mechanical properties of the epoxy, enabling it to expand and contract with temperature changes without fracturing.

Inventive Principle:
Principle #35Parameter changes

2Strength

If tubesheets are made more flexible to resist cracking, then thermal stress resistance improves, but manufacturing precision may be compromised

Engineering Contradiction:
Improveflexibility under stressVSAvoidtubesheet dimensional stability
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent achieves different properties in different aspects of the tubesheet material. The aluminum flake filler provides flexibility and thermal conductivity in the bulk material, while the epoxy resin matrix maintains dimensional stability and precision at the molecular level, allowing the tubesheet to be both flexible and dimensionally accurate.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The filled epoxy tubesheets effectively reduce the likelihood of cracking and leakage, maintaining separation selectivity by deforming rather than cracking under thermal stress, thus enhancing the performance and durability of ASMs.

Implementation Method 1

The temperature fluctuation may result in tubesheet cracks after a few thermal cycles

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 2

incorporating a polymer component and a fill component to provide flexibility and minimize creep

Methodology Applied
Scientific EffectCreep: Creep

Data Source

PatentUS7867319B2Filled epoxy tubesheet
Publication Date: 2011.01.11 HONEYWELL INTERNATIONAL INC
  • US7867319B2 patent drawing
  • US7867319B2 patent drawing
  • US7867319B2 patent drawing

AI summary

A filled epoxy tubesheet comprises an epoxy filled with a metal, such as aluminum flakes. Embodiments of the filled epoxy tubesheets can bend due to stress on the surface rather than crack. Embodiments of the filled epoxy tubesheet can be used to improve Air Separation Module performance by reducing or eliminating leakage through crack in the tubesheet.