Filtration Membrane Stability at Extreme pH

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Solution Overview

Problem

Existing methods for producing filtration membranes with nanofiltration properties are technically complex and expensive, and the resulting membranes are not stable at extreme acidic pH values.

Innovation Solution

A method involving a textile composite coated with hydrophilized polyether sulfone, treated with an aqueous medium containing polyethylene glycol and an aliphatic alcohol, followed by drying, to produce a filtration membrane with an average molecular cut-off of less than 1000 g/mol, enhancing stability and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If interfacial polymerization is used to produce nanofiltration membranes, then nanofiltration properties are achieved, but the process becomes technically complex and expensive

Engineering Contradiction:
Improvenanofiltration separation performanceVSAvoidproduction process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the fundamental production parameter from interfacial polymerization to a physical coating and drying process. The patent applies a solution containing polyethersulfone and polyethylene glycol to a support membrane, then dries it to form the nanofiltration layer. This parameter change eliminates the complexity of interfacial polymerization while achieving the desired nanofiltration separation performance with a molecular weight cut-off of less than 1000 g/mol.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If interfacial polymerization is used to produce nanofiltration membranes, then nanofiltration properties are achieved, but production costs increase

Engineering Contradiction:
Improvenanofiltration separation performanceVSAvoidproduction cost
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The invention changes the production method from costly interfacial polymerization to a simpler coating and drying process using readily available materials like polyethersulfone and polyethylene glycol. This parameter change significantly reduces production costs while maintaining nanofiltration performance, making the process more economically viable for industrial application.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If conventional nanofiltration membranes are produced, then separation performance is achieved, but stability at extreme acidic pH values is insufficient

Engineering Contradiction:
Improvemolecular cut-off separationVSAvoidstability at extreme pH
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The invention uses a composite material system consisting of polyethersulfone as the base polymer and polyethylene glycol as an additive in specific proportions. This composite formulation creates a nanofiltration membrane that achieves both the required molecular weight cut-off of less than 1000 g/mol and enhanced stability at extreme acidic pH values, overcoming the limitation of conventional nanofiltration membranes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces filtration membranes with high salt rejection and stability at extreme pH values, reducing production costs and complexity, and achieving effective separation of molecules with a molar mass less than 1000 g/mol.

Implementation Method 1

a filtration membrane with an average molecular cut-off of < 1000 g/mol

Methodology Applied
Scientific EffectSize exclusion: Nanopore

Implementation Method 2

Filtration membranes are often hydrophilized to improve fouling properties or increase performance

Methodology Applied
Scientific EffectHydrophilization: Hydrophile

Data Source

PatentEP3145627B1Method for producing a filtration membrane with an average molecular cut-off of &lt; 1000 g/mol
Publication Date: 2020.02.19 LANXESS DEUTSCHLAND GMBH
  • EP3145627B1 patent drawing
  • EP3145627B1 patent drawing
  • EP3145627B1 patent drawing

AI summary

The invention relates to a method for producing a filtration membrane having a mean molecular weight cut-off of &lt; 1000 g/mol.