Fine Pattern Formation Using Etching Gas Protection Films

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The existing fine pattern forming methods, such as the LLE process, face challenges in reducing the number of processes and achieving consistent critical dimension values between first and second patterns due to the deposition of a silicon oxide film, which can deform the first pattern and result in varying etching rates.

Innovation Solution

A method involving the formation of a protection film using reaction products of etching gases on the first photoresist patterns, followed by the creation of second photoresist patterns with a shifted pitch, and subsequent trimming and etching, reduces the number of processes and ensures consistent critical dimension values by using etching gases like fluorocarbon and halogen-containing gases.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a silicon oxide film is deposited on the first pattern to protect it during second photoresist formation, then the first pattern is protected from dissolution, but the number of processes increases and the first pattern may be deformed

Engineering Contradiction:
Improveprotection of first patternVSAvoidnumber of processes
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent extracts the protective function from a separate silicon oxide film deposition process and integrates it into the etching process itself. The protection film is formed in-situ during etching by controlling etching gas flow rates, eliminating the need for a separate deposition process while maintaining pattern protection.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent merges the protection film formation step with the etching process. By adjusting etching gas composition and flow rates, the protection film is deposited simultaneously with etching operations, combining two previously separate processes into one unified operation.

Inventive Principle:
Principle #5Merging (Combining)

2Reliability

If a silicon oxide film is deposited on the first pattern, then the first pattern is protected, but the etching rate varies between first and second patterns resulting in inconsistent critical dimension values

Engineering Contradiction:
Improveprotection of first patternVSAvoidcritical dimension consistency
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the parameters of the etching process, specifically the gas flow rates of CF4 and C2F6. By optimizing these parameters, the protection film has controlled etching characteristics that allow both first and second patterns to be etched at consistent rates, achieving uniform critical dimension values across all patterns.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the number of processes is reduced in the LLE process, then production cost is reduced, but it becomes difficult to protect the first pattern and maintain pattern integrity

Engineering Contradiction:
Improvereduction of production costVSAvoidpattern integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The etching gas system is given multiple functions: it performs both the etching of underlying layers and the formation of the protection film. By selecting appropriate gases (CF4 and C2F6) and controlling their flow rates, the same process equipment and gas delivery system accomplish both protective and etching functions without requiring additional dedicated equipment or processes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach minimizes process variations, maintains pattern integrity, and achieves consistent critical dimension values, enhancing the precision and efficiency of fine pattern formation below the photolithography resolution limit.

Implementation Method 1

a protection film is formed by depositing reaction products of an etching gas on the trimmed first patterns

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

depositing reaction products of an etching gas on the trimmed first patterns

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

etching the film using the first patterns and the second patterns

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 4

etching gases like fluorocarbon and halogen-containing gases

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Data Source

PatentUS8273258B2Fine pattern forming method
Publication Date: 2012.09.25 TOKYO ELECTRON LTD
  • US8273258B2 patent drawing
  • US8273258B2 patent drawing
  • US8273258B2 patent drawing

AI summary

A disclosed fine pattern forming method includes steps of: forming patterns made of a first photoresist film, arranged at a first pitch on a film; trimming the patterns made of the first photoresist film; depositing a protection film on the patterns made of the first photoresist film on the trimmed patterns made of the first photoresist film, the protection film being made of reaction products of an etching gas, thereby obtaining first patterns; forming other patterns made of a second photoresist film, arranged at a second pitch, on the protection film, the other patterns made of the second photoresist film being shifted by half of the first pitch from the corresponding patterns made of the first photoresist film; trimming the other patterns made of the second photoresist film into second patterns; and etching the film using the first patterns and the second patterns.