FinFET Source/Drain Epitaxy With As Barrier for P Diffusion Control

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Solution Overview

Problem

In Fin FET devices, phosphorus (P) diffusion from the SiP source/drain epitaxial layer into the channel region is not adequately suppressed, leading to performance issues, and existing methods are insufficient to prevent P out-diffusion effectively.

Innovation Solution

An arsenic (As) containing layer is used as a P diffusion barrier, either grown as a first epitaxial layer or implanted, and additional As containing layers are formed to prevent P out-gassing during contact metallization, with specific epitaxial layers and implantation processes to control the concentration and distribution of As and P.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If higher P concentration is used in SiP source/drain epitaxial layer, then resistivity is reduced and device performance is improved, but P diffusion into channel region increases and reliability deteriorates

Engineering Contradiction:
Improvedevice reliabilityVSAvoidP diffusion into channel
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

An arsenic-containing barrier layer is introduced as an intermediary between the SiP source/drain epitaxial layer and the channel region. This barrier layer acts as a mediator that prevents phosphorus diffusion into the channel while allowing the high P concentration in SiP to maintain low resistivity. The barrier layer is formed by implanting As ions or depositing an As-containing layer before forming the SiP epitaxial layer.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The arsenic-containing barrier layer is formed in advance before the SiP source/drain epitaxial layer is deposited. This preliminary action establishes the diffusion barrier beforehand, preventing P diffusion during subsequent processing steps such as annealing or metallization. The barrier layer is prepared as part of the source/drain region formation process before final contact metallization is applied.

Inventive Principle:
Principle #10Preliminary action

2Object-affected harmful factors

If conventional diffusion barrier methods are used, then P diffusion is partially suppressed, but the barrier is insufficient to prevent P out-diffusion during contact metallization

Engineering Contradiction:
ImproveP diffusion suppressionVSAvoidP out-diffusion prevention
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention changes the material parameter of the diffusion barrier from conventional materials to an arsenic-containing layer with specific properties. The As-containing layer has a different atomic mass and bonding characteristics that provide superior P diffusion blocking capability. The barrier layer may have specific thickness (e.g., 1-10 nm) and As concentration parameters that are optimized to prevent both P diffusion into the channel and P out-diffusion during metallization.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The source/drain region is structured as a composite material system consisting of multiple layers: the SiP epitaxial layer, the As-containing barrier layer, and contact metallization layers. This composite structure combines materials with complementary properties - SiP provides low resistivity, As-layer provides diffusion blocking, and metallization provides electrical contact. The composite structure enables simultaneous achievement of low resistivity and effective P diffusion prevention.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The As containing layers effectively prevent P diffusion into the channel region, allowing for higher P concentration in the SiP body to reduce resistivity and prevent P out-gassing during metallization, thereby enhancing the reliability and performance of Fin FET devices.

Implementation Method 1

An As containing layer is formed over a source/drain region of a semiconductor layer to prevent diffusion of P into a channel region

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

a first epitaxial layer is formed over the source/drain region, a second epitaxial layer is formed over the first epitaxial layer, and a third epitaxial layer is formed over the second epitaxial layer

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS11990510B2Semiconductor device and manufacturing method thereof
Publication Date: 2024.05.21 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11990510B2 patent drawing
  • US11990510B2 patent drawing
  • US11990510B2 patent drawing

AI summary

A semiconductor device, includes a channel region, and a source/drain region adjacent to the channel region. The source/drain region includes a first epitaxial layer, a second epitaxial layer epitaxially formed on the first epitaxial layer and a third epitaxial layer epitaxially formed on the second epitaxial layer, and the first epitaxial layer is made of SiAs.