FinFET Gate Stack Passivation Through N-Type Work Function Metal

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Solution Overview

Problem

As semiconductor devices, such as FinFETs, continue to shrink in feature size, they face challenges with defects in gate dielectric layers that affect device performance and reliability, including dangling bonds and oxygen vacancies, which existing technologies struggle to address effectively without damaging the transistor.

Innovation Solution

A remote plasma process is used to introduce passivating species like fluorine or nitrogen radicals into the gate dielectric layers, which are facilitated by an n-type work function metal to improve conformity and doping concentration, and can be performed at low temperatures to minimize damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional passivation treatments are used on gate dielectric layers, then defects like dangling bonds and oxygen vacancies can be addressed, but the transistor may suffer from thermal damage

Engineering Contradiction:
Improvedevice reliabilityVSAvoidthermal damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the temperature parameter from conventional high-temperature processes to low-temperature plasma treatment (below 200°C), enabling effective defect passivation without causing thermal damage to the transistor structure. This parameter change resolves the contradiction between achieving reliable defect fixation and avoiding thermal harm.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces thermal-based passivation mechanisms with plasma-based chemical treatment. Instead of using heat to activate passivation reactions, the invention uses reactive species in plasma to chemically passivate defects at low temperatures, substituting a thermal system with a chemical plasma system that avoids thermal damage.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If feature sizes are reduced to increase integration density, then more components can be integrated, but defects in gate dielectric layers become more prevalent

Engineering Contradiction:
Improveintegration densityVSAvoiddevice performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary passivation treatment to gate dielectric layers before subsequent processing steps. By pre-passivating defects in the gate dielectric at low temperature, the invention prepares the structure to maintain reliability even as feature sizes are reduced for higher integration density, addressing the contradiction between scaling and defect prevalence.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If high temperature processes are used for passivation treatment, then defect fixation may be more effective, but the risk of damaging the transistor increases

Engineering Contradiction:
Improvedefect fixation qualityVSAvoidtransistor damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent fundamentally changes the temperature parameter from high temperature to low temperature (below 200°C) while maintaining effective defect fixation through plasma chemistry. This parameter change enables achieving manufacturing precision for defect fixation without incurring the harmful effect of transistor damage from excessive heat.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces plasma as an intermediary medium to transfer passivation capability without requiring high temperature. The reactive species in plasma act as intermediaries that can chemically passivate defects at low temperatures, mediating between the need for effective defect fixation and the constraint of avoiding thermal damage.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively fixes defects in the gate dielectric layers, enhancing device performance and reliability by improving the film quality and reducing the risk of thermal damage during the passivation treatment.

Implementation Method 1

A remote plasma process is used to introduce passivating species like fluorine or nitrogen radicals into the gate dielectric layers

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

introduce passivating species like fluorine or nitrogen radicals into the gate dielectric layers

Methodology Applied
Scientific EffectRadicals:

Implementation Method 3

an n-type work function metal to improve conformity and doping concentration

Methodology Applied
Scientific EffectDoping: Dopants

Data Source

PatentUS11756832B2Gate structures in semiconductor devices
Publication Date: 2023.09.12 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11756832B2 patent drawing
  • US11756832B2 patent drawing
  • US11756832B2 patent drawing

AI summary

A method includes depositing a high-k gate dielectric layer over and along sidewalls of a semiconductor fin. The method further includes depositing an n-type work function metal layer over the high-k gate dielectric layer and performing a passivation treatment on the high-k gate dielectric layer through the n-type work function metal layer. The passivation treatment comprises a remote plasma process. The method further includes depositing a fill metal over the n-type work function metal layer to form a metal gate stack over the high-k gate dielectric layer. The metal gate stack comprising the n-type work function metal layer and the fill metal.