Fire Extinguishing Composition for Wetting Porous Burning Surfaces

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Solution Overview

Problem

Existing fire extinguishing agents are inefficient in extinguishing fires on both hydrophilic and hydrophobic surfaces, particularly solid and porous materials like wood, and do not effectively block oxygen supply or reduce surface temperature.

Innovation Solution

Aqueous solution comprising a surfactant, specifically 3-(3-hydroxypropyl)-heptamethyltrisiloxane ethoxylated hydroxyl terminated, and a deliquescent anionic salt, such as calcium chloride, with a specific concentration, which minimizes surface tension and contact angle, allowing for rapid spreading, penetration, and wetting without foaming, thereby blocking oxygen supply and reducing surface temperature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If water is used as fire extinguishing medium, then cooling effect is achieved, but water evaporates and burning surface reignites

Engineering Contradiction:
Improvesurface temperatureVSAvoidfire extinguishing effectiveness
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent introduces an intermediary substance (fire extinguishing composition containing surfactant and deliquescent salt) that mediates between water and burning surface. The composition forms a stable film that transfers heat from burning surface to water without evaporating, preventing reignition while maintaining cooling effect

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent utilizes phase transition principles by controlling the evaporation process. The deliquescent salt absorbs moisture from evaporating water, preventing complete vaporization and maintaining liquid film on burning surface, thus preventing reignition through controlled phase transition management

Inventive Principle:
Principle #36Phase transitions

2Reliability

If foaming agents are used to prevent burning liquid vaporization, then fire extinguishing efficiency improves, but foaming prevents complete distribution on solid rough porous surfaces

Engineering Contradiction:
Improvefire extinguishing efficiencyVSAvoidsurface compatibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent changes the physical parameters of the extinguishing medium by using a deliquescent salt that absorbs moisture and forms a gel-like structure. This parameter change allows the composition to adapt to different surface types (solid, rough, porous) while maintaining fire extinguishing efficiency, eliminating the need for foaming agents

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite fire extinguishing composition by combining surfactant and deliquescent salt in aqueous solution. This composite material exhibits properties that enable complete distribution on various surface types while maintaining fire suppression effectiveness, overcoming the limitations of conventional foaming agents

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional fire extinguishing agents are used, then fire suppression is achieved, but oxygen supply to burning surface is not effectively blocked

Engineering Contradiction:
Improvefire suppression capabilityVSAvoidoxygen supply to burning surface
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent utilizes the surfactant to form a flexible thin film on the burning surface. This film acts as a barrier that blocks oxygen supply while allowing heat transfer to water, effectively suppressing fire by cutting off the oxygen component of the combustion triangle

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively extinguishes fires on both hydrophilic and hydrophobic surfaces by blocking oxygen supply and rapidly reducing surface temperature, with minimal foaming and environmental impact.

Implementation Method 1

The aqueous solution has extremely low surface tension (which means that water molecules have higher mobility and migrating properties) and a contact angle of 0° and so, it is very good in spreading, penetration and wetting

Methodology Applied
Scientific EffectSurface tension reduction by surfactant: Surfactant

Implementation Method 2

the deliquescent anionic salt is present at a concentration of 5% by weight

Methodology Applied
Scientific EffectDeliquescence: Deliquescence

Data Source

PatentEP4025307B1Composition and method for extinguishing fire
Publication Date: 2026.02.25 CHOO HIOW SAN
  • EP4025307B1 patent drawingFigure 1~2
  • EP4025307B1 patent drawingFigure 3A~3B
  • EP4025307B1 patent drawing

AI summary

The present invention relates to a composition for extinguishing fire, comprising an aqueous solution of a surfactant and a deliquescent anionic salt. A method for extinguishing fire is also disclosed. The method (100) comprises mixing a surfactant and a deliquescent anionic salt in water to form an aqueous solution (110) and spreading the aqueous solution over a burning surface (120).