Fireproof Composition Using Carbon Nanotubes and Polysiloxane

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Solution Overview

Problem

Traditional fire-resistant coatings and seals in aeronautics face challenges due to high filler content, which compromises flexibility and mechanical properties, and existing fire-resistant materials' seals melt before critical temperatures, reducing the fireproof advantage.

Innovation Solution

A composition of reticulated polysiloxane with raw carbon nanotubes, where the carbon nanotubes represent 0.05-1% of the total weight, providing excellent heat resistance and flexibility, allowing for easy application as a coating or seal, achieved through a method involving the production of a mixture with polysiloxane and hydrosilane groups, followed by reticulation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional fire-resistant coatings use high filler content to improve fire resistance, then fire-resistant properties are improved, but mechanical properties and flexibility deteriorate

Engineering Contradiction:
Improvefire-resistant propertiesVSAvoidmechanical properties
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a composite material system combining polysiloxane polymer with carbon nanotubes and phyllosilicates. This composite structure provides fire resistance through the inorganic fillers while the polymer matrix maintains mechanical flexibility and strength, resolving the contradiction between fire resistance and mechanical properties

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the filler content parameters, specifically limiting total filler to 10-60% by volume with carbon nanotubes at 1-30% and phyllosilicates at 1-50%, rather than using traditional high filler content. This parameter optimization maintains fire resistance while preserving mechanical properties and flexibility

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional fire-resistant coatings use high filler content to improve fire resistance, then fire-resistant properties are improved, but flexibility and ease of application deteriorate

Engineering Contradiction:
Improvefire-resistant propertiesVSAvoidflexibility and ease of application
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The composite of polysiloxane with controlled filler content creates a material that is both fire-resistant and sufficiently flexible for application. The polymer matrix provides flexibility while the fillers provide fire resistance, enabling the coating to follow thermal expansion and movement without cracking

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By controlling the total filler content to 10-60% and specifically limiting carbon nanotubes to 1-30%, the patent achieves a balance where the coating remains flexible enough for application by spraying or brushing while maintaining fire-resistant properties

Inventive Principle:
Principle #35Parameter changes

3Reliability

If seals use traditional materials to achieve fire resistance, then fire-resistant properties are improved, but temperature resistance before melting deteriorates

Engineering Contradiction:
Improvefire-resistant propertiesVSAvoidtemperature resistance before melting
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent uses a composite seal material combining polysiloxane with carbon nanotubes and phyllosilicates. This composite structure raises the melting temperature and maintains structural integrity at high temperatures better than traditional seal materials, while still providing fire resistance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the composition parameters of the seal material, using specific ratios of carbon nanotubes (1-30%) and phyllosilicates (1-50%) within the polysiloxane matrix to achieve both fire resistance and high temperature resistance, preventing premature melting

Inventive Principle:
Principle #35Parameter changes

4Strength

If polymer-based coatings use pasty consistency to improve adhesion, then adhesion is improved, but ease of application by spraying deteriorates

Engineering Contradiction:
ImproveadhesionVSAvoidease of application by spraying
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent modifies the viscosity and consistency parameters of the polymer-based coating by controlling filler content and using polysiloxane as the base polymer. This allows the coating to be applied by spraying while maintaining adequate adhesion properties after curing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition exhibits improved viscosimetric properties for easy application and significant fire-resistant effects, maintaining attachment and heat resistance with low filler levels, as demonstrated by temperature tests and viscosity measurements.

Implementation Method 1

delay the heating up of the metal part that it protects as much as possible

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 2

carbon nanotubes be incorporated into the polymer

Methodology Applied
Scientific EffectHeat absorption: Absorption (EM radiation)

Implementation Method 3

filled with a substance likely to react to the heat and to form a passivation layer protecting the metal parts from a too fast heating

Methodology Applied
Scientific EffectPassivation layer formation:

Implementation Method 4

The composition according to the invention has surprising viscosimetric and fire-resistant properties

Methodology Applied
Scientific EffectHeat resistance: Thermal Insulation

Data Source

PatentUS9290676B2Fireproof composition
Publication Date: 2016.03.22 NANOCYL SA
  • US9290676B2 patent drawing
  • US9290676B2 patent drawing
  • US9290676B2 patent drawing

AI summary

The present invention concerns a fireproof composition consisting of reticulated polysiloxane and raw carbon nanotubes with a “bound rubber” value greater than or equal to 15 grams of carbon nanotube, said carbon nanotubes representing between 0.05 and 1% of the total weight of said composition.