Fischer-Tropsch Waxes in Bitumen Polymer Compositions

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Solution Overview

Problem

Conventional bitumen/polymer compositions used in road surfaces are susceptible to rapid deterioration due to chemical attacks from hydrocarbon solvents and de-icing/defrosting fluids, leading to increased maintenance needs and reduced lifespan, especially in high-traffic and harsh weather conditions.

Innovation Solution

Incorporating 2% to 6% Fischer-Tropsch waxes into crosslinked bitumen/polymer compositions, specifically those with a crosslinked copolymer of styrene and butadiene, enhances resistance to petroleum hydrocarbons and de-icing fluids, demonstrating a synergistic effect that improves mechanical properties and chemical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional bitumen/polymer compositions are used in road surfaces, then mechanical properties are maintained, but resistance to chemical attack from hydrocarbon solvents and de-icing fluids deteriorates rapidly

Engineering Contradiction:
Improvechemical resistanceVSAvoidservice lifespan
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent combines bitumen with crosslinked polymer (styrene-butadiene copolymer) and Fischer-Tropsch wax to create a composite material that leverages the chemical resistance of the crosslinked polymer network and the hydrophobic properties of the wax, achieving superior resistance to hydrocarbon solvents and de-icing fluids while maintaining mechanical integrity and extending service lifespan

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters by incorporating specific amounts of crosslinked polymer (2-8% by mass) and Fischer-Tropsch wax (2-6% by mass) to transform the bitumen's chemical resistance properties, enabling it to withstand aggressive chemical environments without rapid deterioration

Inventive Principle:
Principle #35Parameter changes

2Reliability

If Fischer-Tropsch waxes are added to bitumen, then resistance to hydrocarbon solvents improves, but the synergistic effect with crosslinked polymer is not fully utilized

Engineering Contradiction:
Improveresistance to petroleum hydrocarbonsVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of Fischer-Tropsch wax (hydrocarbon resistance) and crosslinked polymer (structural integrity and chemical stability) into a unified bitumen composition, creating a synergistic effect where the combined performance exceeds the sum of individual contributions, thereby improving resistance to petroleum hydrocarbons without proportionally increasing complexity

Inventive Principle:
Principle #5Merging (Combining)

Data Source

PatentEP2493986B1Use of waxes in a bitumen/crosslinked polymer composition in order to improve the resistance thereof to chemical attack, and bitumen/crosslinked polymer composition comprising said waxes
Publication Date: 2018.12.05 TOTALENERGIES ONETECH
  • EP2493986B1 patent drawing

AI summary

The invention relates to the use of 2 - 6 wt.-% Fischer-Tropsch waxes in a bitumen/crosslinked polymer composition in order to improve the resistance of the composition to aggressive chemical agents.