Hydrothermal Conversion of Fish Scales to Carbon Dots and Hydroxyapatite

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Solution Overview

Problem

The management of fish waste from the fish industry poses a significant global challenge due to its hazardous nature and high chemical and biological oxygen demands, and there is a need for a method to convert this waste into useful nanostructures for biomedical applications.

Innovation Solution

A single hydrothermal process is used to treat fish scales, producing carbon dots and hydroxyapatite nanostructures, where the carbon dots can be used for fluorescent imaging and the hydroxyapatite for tissue engineering, leveraging the natural composition of fish scales which include chitin, hydroxyapatite, and collagen.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If fish waste is disposed of through conventional methods, then the environmental pollution problem is temporarily managed, but the high chemical oxygen demand and biological oxygen demand continue to harm the environment

Engineering Contradiction:
Improveenvironmental pollutionVSAvoidchemical oxygen demand and biological oxygen demand
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent converts fish waste, which is harmful due to its high chemical oxygen demand and biological oxygen demand, into beneficial nanostructures (carbon dots and hydroxyapatite) through hydrothermal carbonization. This transformation eliminates the harmful effects of fish waste while producing valuable materials for biomedical applications, directly applying the principle of converting harm into benefit.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Manufacturing precision

If multiple sequential processes are used to extract different biomaterials, then the purity and quality of each material is improved, but the processing time and complexity increase significantly

Engineering Contradiction:
Improvematerial purity and qualityVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent merges multiple extraction processes into a single hydrothermal carbonization step that simultaneously produces carbon dots and hydroxyapatite nanostructures from fish waste. This consolidation maintains material quality while dramatically reducing processing time and operational complexity, directly applying the principle of merging multiple processes into one.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The hydrothermal carbonization process serves multiple functions simultaneously: it extracts carbon dots, extracts hydroxyapatite nanostructures, and eliminates the need for separate processing steps. This multi-functionality resolves the contradiction by achieving high material quality through a single universal process rather than multiple sequential extractions.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Adaptability or versatility

If fish waste is converted into valuable products, then the economic value is improved, but the processing complexity and infrastructure requirements increase

Engineering Contradiction:
Improveeconomic value of fish wasteVSAvoidprocessing infrastructure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent transforms low-value harmful fish waste into high-value biomedical materials (carbon dots for imaging and hydroxyapatite for tissue engineering) through a relatively simple hydrothermal carbonization process. This conversion dramatically increases economic value while avoiding complex processing infrastructure, directly applying the principle of converting harm into benefit.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses hydrothermal carbonization, which operates under controlled temperature and pressure parameters, to convert fish waste into valuable nanostructures. By optimizing these physical parameters rather than requiring complex chemical processing infrastructure, the method achieves high economic value with relatively simple processing requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively produces biocompatible nanostructures that are non-toxic and suitable for cellular imaging and tissue engineering applications, demonstrating good viability and biocompatibility in cytotoxicity assays and exhibiting excitation-dependent photoluminescence.

Implementation Method 1

treating fish scales using a single hydrothermal process to simultaneously produce two distinct nanostructures, carbon dots (C-dots) and hydroxyapatite

Methodology Applied
Scientific EffectHydrothermal carbonization:

Implementation Method 2

the C-dots exhibit excitation dependent photoluminescence

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS10383976B1Method of fabricating nanostructures from fish waste
Publication Date: 2019.08.20 KING SAUD UNIVERSITY
  • US10383976B1 patent drawing
  • US10383976B1 patent drawing
  • US10383976B1 patent drawing

AI summary

The fabrication of nanostructures from fish waste is a method of co-fabricating C-dots and hydroxyapatite from fish scales. The method includes hydrothermal treatment of fish scales to simultaneously produce hydroxyapatite nanostructures and C-dot nanostructures. The C-dots may be used as probes for fluorescent imaging. The hydroxyapatite nanostructures may be used for tissue engineering applications.