Amine Hole Transport Layer for Low-Voltage OLED Lifespan

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in reducing driving voltage, enhancing emission efficiency, and extending lifespan, particularly in the development of effective hole transport materials.

Innovation Solution

Incorporating an amine compound with a five-ring condensed hetero compound as a substituent, which includes one nitrogen atom and two oxygen atoms, into the organic electroluminescence device's hole transport layer to improve hole transport efficiency and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional hole transport materials are used, then the device can operate, but the driving voltage is high and the emission efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidemission efficiency
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the molecular structure of hole transport materials by introducing a five-ring condensed hetero compound with specific nitrogen and oxygen atoms. This structural parameter change optimizes the material's electronic properties, enabling lower driving voltage and higher emission efficiency simultaneously through improved charge transport and reduced energy loss.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite hole transport material by combining the amine compound with the five-ring condensed hetero compound substituent. This composite structure integrates the benefits of both components: the amine group provides hole transport capability while the hetero compound substituent enhances stability and reduces voltage requirements, achieving high emission efficiency.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional hole transport materials are used, then the device can operate, but the lifespan is short due to material damage from extra charges

Engineering Contradiction:
Improvedevice lifespanVSAvoidmaterial damage from extra charges
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The patent addresses the harmful effect of extra charges causing material degradation by incorporating the five-ring condensed hetero compound with nitrogen and oxygen atoms into the hole transport material. This substitution converts the potentially harmful charge accumulation into a beneficial effect where the hetero atoms facilitate charge delocalization and reduce localized stress, thereby protecting the material and extending device lifespan.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

By changing the chemical composition parameter of the hole transport material to include the specific hetero compound substituent, the material's resistance to charge-induced degradation is enhanced. The nitrogen and oxygen atoms in the five-ring condensed structure modify the electronic distribution, reducing the harmful effects of extra charges and improving long-term device stability.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the hole transport layer uses standard materials, then the device structure is simple, but the light emitting efficiency is insufficient

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies local quality modification by introducing the five-ring condensed hetero compound substituent specifically at the amine group position in the hole transport material. This localized structural enhancement targets the charge transport region, improving light emitting efficiency where it is most needed without requiring complex changes throughout the entire device structure.

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS11770973B2Organic electroluminescence device and amine compound for organic electroluminescence device
Publication Date: 2023.09.26 SAMSUNG DISPLAY CO LTD
  • US11770973B2 patent drawing
  • US11770973B2 patent drawing
  • US11770973B2 patent drawing

AI summary

An organic electroluminescence device of an embodiment includes a first electrode and a second electrode which are faced to each other, and a plurality of organic layers between the first electrode and the second electrode, and at least one organic layer selected from among the organic layers includes an amine compound represented by Formula 1 below, and thus, the organic electroluminescence device can exhibit improved emitting efficiency and long device lifespan.