Flame Deposition Nanotextured Surfaces for Hydrophobic Coatings

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Solution Overview

Problem

Current methods for producing nanotextured surfaces with high water contact angles for self-cleaning applications are limited by mechanical stability and adhesion strength, leading to loss of hydrophobic properties over time due to erosion or removal of nanoscale texture, and are costly and complex to implement on a large scale.

Innovation Solution

A method involving flame deposition to form nanoparticles on a substrate, where a precursor is introduced into a carrier gas stream, heated, and nanoparticles are delivered to the substrate to create a nanotextured surface that is sintered onto the substrate, achieving high water contact angles and maintaining hydrophobic properties through abrasion testing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional etching or coating processes are used to create nanotextured surfaces, then water contact angles can be increased beyond 120°, but the processing complexity and cost increase significantly

Engineering Contradiction:
Improvewater contact angleVSAvoidprocessing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention changes the processing parameters from conventional etching/coating methods to flame deposition, using a flame environment to simultaneously achieve nanotexture formation and hydrophobic coating in a single step, thereby reducing processing complexity while maintaining high water contact angles

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention merges the nanotexture creation and hydrophobic coating steps into a single flame deposition process, where nanoparticles are deposited and sintered simultaneously, eliminating the need for separate etching and coating operations

Inventive Principle:
Principle #5Merging (Combining)

2Manufacturing precision

If nanotextured coatings are produced by conventional methods, then high water contact angles are achieved, but mechanical stability and adhesion strength become insufficient

Engineering Contradiction:
Improvewater contact angleVSAvoidadhesion strength
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The invention utilizes phase transition of nanoparticles through sintering in the flame environment, transforming loose nanoparticles into a mechanically stable, sintered nanotextured layer that maintains both high water contact angles and strong adhesion to the substrate

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The invention creates a composite structure where nanoparticles are embedded in a matrix formed during flame deposition, producing a nanotextured coating with enhanced mechanical stability and adhesion strength while maintaining the hydrophobic surface properties

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If nanotextured surfaces are created by etching or coating, then contact angles exceed 120°, but the features must be limited to 100-200 nm to maintain substrate transparency

Engineering Contradiction:
Improvewater contact angleVSAvoidfeature size
Core Design Contradiction:
Manufacturing precisionVSLength of moving object

Solution Approach 1:

The invention employs self-assembly of nanoparticles during flame deposition, where particles naturally organize into the required 100-200 nm scale features through thermodynamic processes in the flame environment, eliminating the need for complex top-down fabrication approaches

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces durable nanotextured surfaces with water contact angles greater than 120° that remain adhered and hydrophobic after prolonged abrasive contact, suitable for various applications including anti-icing and anti-fogging glass, and self-cleaning surfaces.

Implementation Method 1

introducing a precursor into a stream of a carrier gas; delivering the nanoparticles to the surface of the substrate facing the carrier gas

Methodology Applied
Scientific EffectFluid flow: Convection

Implementation Method 2

heating the surface of the substrate facing the carrier gas

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

the forming (b) comprises combustion or hydrolysis of the precursor

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 4

the forming (b) comprises combustion or hydrolysis of the precursor

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 5

the nanotextured surface comprises nanoparticles that are sintered to the substrate

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS11752520B2Methods for producing nanotextured surfaces
Publication Date: 2023.09.12 CORNING INC
  • US11752520B2 patent drawing
  • US11752520B2 patent drawing
  • US11752520B2 patent drawing

AI summary

Methods for producing a nanotextured surface on a substrate include forming nanoparticles from a precursor within a stream of a carrier gas. Methods include heating a surface of a substrate facing the carrier gas. Methods comprise delivering the nanoparticles to the surface of the substrate facing the carrier gas to produce the nanotextured surface.