Flash Drum Oligomerate Separation for Utility Cost Reduction

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Solution Overview

Problem

The existing processes for oligomerizing light olefins face challenges in producing high-quality gasoline and diesel efficiently, as catalysts for high octane gasoline produce undesirable diesel products and vice versa, and recycling heavy oligomers to maintain a liquid phase in reactors is costly due to high utility expenses.

Innovation Solution

A process and apparatus that utilize a flash drum to separate heavy and light oligomerates, allowing the light oligomerate to bypass fractionation columns and recycle the heavy oligomerate back to the oligomerization zone, reducing operational expenses by minimizing utility costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If heavy oligomerate is recycled to maintain liquid phase in oligomerization reactor, then catalyst stability and activity are improved, but utility costs and operational expenses increase significantly

Engineering Contradiction:
Improvecatalyst stabilityVSAvoidutility costs
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The flash drum separates the oligomerate stream into heavy and light fractions, allowing selective recycling of only the heavy oligomerate portion. This segmentation enables maintaining catalyst stability while reducing the energy-intensive recycling of lighter, less valuable fractions that don't contribute as much to liquid phase maintenance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different portions of the oligomerate stream are treated differently - heavy oligomerate is recycled to maintain liquid phase and catalyst stability, while light oligomerate is sent to fractionation or other processing. This local quality approach optimizes utility usage by applying recycling only where it provides the most benefit.

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If heavy oligomerate is separated and recycled through fractionation column, then separation efficiency is improved, but operational expenses and utility costs increase

Engineering Contradiction:
Improveseparation efficiencyVSAvoidoperational efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The flash drum performs a preliminary segmentation of the oligomerate stream into heavy and light fractions before fractionation. This pre-separation reduces the burden on the fractionation column, allowing it to focus on finer separations of the light fraction, thereby improving overall separation efficiency while reducing operational expenses.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The flash drum performs a preliminary separation action before the main fractionation process. By removing the heavy oligomerate fraction first, the subsequent fractionation column only needs to process the lighter fractions, reducing its operational burden and utility consumption while maintaining separation efficiency.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If all oligomerate is sent to fractionation column for separation, then product purity is improved, but utility costs and operational expenses increase

Engineering Contradiction:
Improveproduct purityVSAvoidutility costs
Core Design Contradiction:
Manufacturing precisionVSUse of energy by moving object

Solution Approach 1:

The heavy oligomerate fraction is extracted from the main oligomerate stream using the flash drum and recycled directly without passing through the fractionation column. This extraction eliminates the need for energy-intensive fractionation of this fraction while still achieving the desired product purity through selective recycling of only the necessary heavy components.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The oligomerate stream is segmented into heavy and light fractions, with only the heavy fraction requiring recycling for catalyst stability. This segmentation allows the light fraction to bypass fractionation, reducing utility costs while maintaining sufficient product purity for the heavy fraction that does undergo fractionation.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables efficient recycling of heavy oligomers, reducing utility costs and improving the quality of gasoline and diesel production by optimizing the oligomerization process, thereby enhancing the overall efficiency and cost-effectiveness of the refinery operations.

Implementation Method 1

separating the oligomerate stream from the oligomerization zone in a flash drum to provide a light flash oligomerate stream and a heavy flash oligomerate stream

Methodology Applied
Scientific EffectVapor-liquid equilibrium: Flash Evaporation

Data Source

PatentUS9387413B2Process and apparatus for recovering oligomerate
Publication Date: 2016.07.12 UOP LLC
  • US9387413B2 patent drawing
  • US9387413B2 patent drawing
  • US9387413B2 patent drawing

AI summary

A process and apparatus uses a flash drum to separate light hydrocarbons from heavy oligomerate from an oligomerization zone. The heavy oligomerate can bypass a fractionation column in the oligomerate recovery section and be recycled to the oligomerization zone or other zones. Costs are saved by avoiding repeatedly transporting and processing the heavier recycled oligomerate.