Flash Memory Nitrogen Treatment for Data Retention

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Solution Overview

Problem

As flash memory devices become more integrated and their feature size decreases, they face challenges in maintaining high temperature operating life and data retention reliability due to limitations in the thickness of the linear oxide layer and nitride spacer, which affects their performance.

Innovation Solution

A nitrogen atom-introducing treatment is performed after forming the first oxide layer and before forming the nitride spacer, using a thermal treatment with a nitrogen-containing gas to enhance bonding and repair process damage, thereby improving data retention reliability and integration degree without adding additional layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the thickness of the linear oxide layer and nitride spacer is reduced to increase integration degree, then the memory capacity and integration degree are improved, but the high temperature operating life and data retention reliability deteriorate

Engineering Contradiction:
Improveintegration degreeVSAvoiddata retention reliability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A nitrogen atom-introducing treatment is performed after forming the first oxide layer and before forming the nitride spacer. This preliminary nitrogen introduction strengthens the oxide layer, allowing it to maintain reliability even when the thickness of the oxide layer and nitride spacer is reduced for higher integration.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If the feature size is reduced to increase integration degree, then the memory capacity is improved, but the high temperature operating life deteriorates

Engineering Contradiction:
Improveintegration degreeVSAvoidhigh temperature operating life
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the chemical composition parameter of the oxide layer by introducing nitrogen atoms through a nitrogen atom-introducing treatment. This parameter change strengthens the oxide layer, enabling it to withstand high temperature operations even when the overall device feature size is reduced for higher integration.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nitrogen atom-introducing treatment strengthens the flash memory device's characteristics, increasing high temperature operating life and reducing data retention failures, while enhancing both data retention reliability and integration degree simultaneously.

Implementation Method 1

a nitrogen atom-introducing treatment is performed after the forming of the first oxide layer and before the forming of the nitride spacer

Methodology Applied
Scientific EffectNitrogen atom-introducing treatment: Nitriding

Implementation Method 2

using a thermal treatment with a nitrogen-containing gas to enhance bonding

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS8486781B2Method of manufacturing flash memory device
Publication Date: 2013.07.16 UNITED MICROELECTRONICS CORP
  • US8486781B2 patent drawing
  • US8486781B2 patent drawing
  • US8486781B2 patent drawing

AI summary

A method of manufacturing flash memory device is provided and includes the following steps. First, a substrate is provided. Then, a stacked gate structure is formed on the substrate. Subsequently, a first oxide layer is formed on the stacked gate structure. Following that, a nitride spacer is formed on the first oxide layer, wherein a nitrogen atom-introducing treatment is performed after the forming of the first oxide layer and before the forming of the nitride spacer. Accordingly, the nitrogen atom-introducing treatment of the presentation invention can improve the data retention reliability of the flash memory device.