Flash Vessel Precipitation for Alkaline Earth Metal Recovery

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Solution Overview

Problem

The existing methods for recovering processing liquids from natural gas production are inefficient and costly due to contamination with alkaline earth metal cations, which form water-insoluble salts, leading to fouling in equipment and requiring expensive pre-treatment processes.

Innovation Solution

A process involving a flash vessel with a forced recirculating reboiler loop and introduction of precipitants to form water-insoluble salts, allowing for in-line removal of alkaline earth metal cations during the reclaiming stage, eliminating the need for pre-treatment and enabling efficient separation of processing liquids.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If pre-treatment is applied to remove alkaline earth metal cations before processing liquid recovery, then equipment fouling is reduced, but process complexity and cost increase

Engineering Contradiction:
Improveequipment foulingVSAvoidprocess complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The invention combines the precipitation of alkaline earth metal cations with the existing processing liquid recovery process by introducing precipitants into the flash vessel. This merging eliminates the need for separate pre-treatment equipment while still achieving effective removal of cations that cause fouling, thus reducing device complexity while maintaining the benefit of reduced equipment fouling.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention extracts the harmful alkaline earth metal cations from the feed stream by introducing precipitants that form water-insoluble salts. These precipitated cations are then removed along with water-insoluble salts in the flash separation process, effectively taking out the fouling-causing contaminants without requiring separate pre-treatment systems.

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-generated harmful factors

If pre-treatment is applied to remove alkaline earth metal cations, then salt precipitation is controlled, but space utilization and operational cost increase

Engineering Contradiction:
Improvesalt precipitation controlVSAvoidspace utilization
Core Design Contradiction:
Object-generated harmful factorsVSArea of stationary object

Solution Approach 1:

The invention merges the salt precipitation control function with the flash separation process. By introducing precipitants into the flash vessel, the control of alkaline earth metal cation precipitation is integrated into the existing recovery system, eliminating the need for separate pre-treatment tanks and equipment, thus improving space utilization while maintaining effective salt precipitation control.

Inventive Principle:
Principle #5Merging (Combining)

3Device complexity

If conventional recovery process is used without integrated precipitation, then process simplicity is maintained, but equipment fouling and operational costs increase

Engineering Contradiction:
Improveprocess simplicityVSAvoidequipment fouling
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The invention makes the flash vessel perform the dual function of both flash separation and precipitation of alkaline earth metal cations. By introducing precipitants into the flash vessel, the system uses its existing structure and operation to simultaneously achieve salt precipitation control and cation removal, eliminating the need for additional pre-treatment equipment while maintaining process simplicity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This process effectively separates water-insoluble salts of alkaline earth metal cations from processing liquids, reducing equipment fouling and operational costs by integrating precipitation within the reclaiming stage, thus enhancing the efficiency of processing liquid recovery.

Implementation Method 1

A process involving a flash vessel with a forced recirculating reboiler loop

Methodology Applied
Scientific EffectFlash evaporation: Flash Evaporation

Implementation Method 2

introduction of precipitants to form water-insoluble salts, allowing for in-line removal of alkaline earth metal cations

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentEP3171964B1Process for recovering processing liquids from streams containing alkaline earth metal salts
Publication Date: 2024.09.04 CCR TECHNOLOGIES LTD
  • EP3171964B1 patent drawingFigure 1
  • EP3171964B1 patent drawingFigure 2
  • EP3171964B1 patent drawingFigure 3

AI summary

A process for recovering processing liquids from a feed stream which contains processing fluid, water, and at least one alkaline earth metal cation. The process includes reacting at least one alkaline earth metal cation with a suitable anion to form a substantially water-insoluble salt precipitate, the precipitate being formed in one of a fractionation column having a forced recycle loop or a flash vessel having a forced heated recycle loop.