Flat Steel Activation Layer for Hot Forming

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Solution Overview

Problem

Existing methods for hot forming of flat steel products with corrosion protection coatings require a large amount of resources and result in large crystalline particles on the surface, which hinder the heating process and subsequent phosphating steps.

Innovation Solution

An activated flat steel product with a steel substrate containing specific alloying elements and a corrosion protection coating based on aluminum, featuring an activation layer of phosphorus, sodium, and titanium, which allows for a higher heating rate with minimal resource use and prevents large particle formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a large quantity of crystalline particles is deposited on the surface to enable hot forming, then the heating rate can be improved, but the resource efficiency deteriorates and large crystalline particles hinder subsequent phosphating

Engineering Contradiction:
Improveheating rateVSAvoidresource efficiency
Core Design Contradiction:
SpeedVSLoss of energy

Solution Approach 1:

The invention changes the chemical composition parameters of the surface coating by applying an activation layer with specific ratios of phosphorus (P ≥ 2×Ti), sodium (Ti ≤ Na), and titanium. This chemical parameter modification enables effective heat coupling during hot forming while preventing the formation of large crystalline particles, thus maintaining resource efficiency and enabling subsequent phosphating operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The activation layer acts as an intermediary substance between the steel substrate and the hot forming environment. It mediates the heat transfer process to enable efficient heating while its specific compositional characteristics prevent the formation of harmful large crystalline particles, serving as a bridge that enables both heating efficiency and subsequent phosphating compatibility.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Loss of energy

If an activation layer with specific composition is applied to enable faster heating, then resource consumption is reduced, but the complexity of the coating process increases

Engineering Contradiction:
Improveresource consumptionVSAvoidcoating process complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The activation layer is applied as a preliminary treatment before hot forming and phosphating operations. By pre-establishing the specific compositional ratio (P ≥ 2×Ti, Ti ≤ Na) on the surface, the subsequent hot forming process benefits from optimized heat coupling and reduced resource consumption, while the layered structure remains manageable in complexity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention creates a composite coating structure consisting of the base corrosion protection coating combined with an activation layer containing specific ratios of phosphorus, sodium, and titanium. This composite approach enables the integration of multiple functions (corrosion protection, heat coupling, and phosphating compatibility) while maintaining manageable process complexity through defined compositional guidelines.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If conventional coating methods are used, then the process is simple, but large crystalline particles form on the surface which hinder phosphating

Engineering Contradiction:
Improveprocess simplicityVSAvoidlarge crystalline particle formation
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The invention modifies the chemical parameters of the surface coating by controlling the ratios of phosphorus, sodium, and titanium in the activation layer (P ≥ 2×Ti, Ti ≤ Na). This parameter control prevents the formation of large crystalline particles during heating while maintaining a relatively simple coating application process, thus eliminating the harmful effect without significantly increasing manufacturing complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables faster heating during hot forming with reduced resource consumption and maintains the integrity of subsequent phosphating processes by forming a nearly closed activation layer with optimal heat coupling.

Implementation Method 1

The solution enables faster heating during hot forming with reduced resource consumption and maintains the integrity of subsequent phosphating processes by forming a nearly closed activation layer with optimal heat coupling

Methodology Applied
Scientific EffectHeat coupling: Conduction (thermal)

Implementation Method 2

an aluminum-based corrosion protection coating

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP4339324A1Flat steel product with an activation layer for hot forming
Publication Date: 2024.03.20 THYSSENKRUPP STEEL EUROPE AG PATENTE PATENT DEPARTMENT
  • EP4339324A1 patent drawingFigure 1
  • EP4339324A1 patent drawingFigure 2~3b
  • EP4339324A1 patent drawing

AI summary

The present invention relates to an activated steel flat product comprising a steel substrate and a corrosion protection coating. The activation layer on the surface contains phosphorus, sodium, and titanium, wherein P ≥ 2xTi, P ≥ Na, and Ti ≤ Na. The invention further relates to a hot-formed component manufactured from the activated steel flat product. The layer structure of the corrosion protection coating on the steel substrate (1) of the hot-formed component according to the invention consists of an alloy layer (2), an aluminum base layer (3), and silicon-rich phases (4), which are not bonded to one another and are embedded in the aluminum base layer (3). An oxide layer containing phosphorus (6) is present on the surface. Optionally, the hot-formed component can subsequently be phosphated.