Flexible Blade Coating Head for Shear-Aligned Block Copolymer Films

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Solution Overview

Problem

Current methods for aligning nanostructures in block copolymer films require separate steps for film casting and shear-based orientation, which are time-consuming and not suitable for large-scale production, especially when high-speed film casting is involved.

Innovation Solution

A coating head with a flexible blade that applies shear force during film drying, combining the benefits of 'hard' and 'soft' shear techniques in a single continuous process, allowing for simultaneous film casting and directional alignment of nanostructures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If separate steps for film casting and shear-based orientation are used, then alignment quality is improved, but processing time increases significantly

Engineering Contradiction:
Improvealignment qualityVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent combines film casting and shear-based orientation into a single integrated coating head. The coating head includes a coating device for depositing material and a flexible blade positioned downstream to apply shear forces during the same continuous process, eliminating the need for separate casting and alignment steps while maintaining high alignment quality through in-line shear application.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention enables continuous film formation and alignment in one uninterrupted process. The coating device continuously deposits material onto the substrate while the flexible blade simultaneously applies shear forces to align nanostructures, allowing the useful actions of casting and orientation to occur continuously without interruption or separation into discrete steps.

Inventive Principle:
Principle #20Continuity of useful action

2Manufacturing precision

If hard shear orientation is applied by lateral displacement of PDMS pad, then alignment is achieved, but the process is time-consuming and unsuitable for high-speed production

Engineering Contradiction:
ImprovealignmentVSAvoidproduction speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent employs a flexible blade that can dynamically adapt to the substrate and film during the coating process. The blade's flexibility allows it to conform to surface variations while maintaining consistent shear force application, enabling effective alignment even at high coating speeds where rigid systems would fail to maintain proper contact and force distribution.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The flexible blade acts as an intermediary between the coating device and the film, transferring shear forces efficiently during the coating process. This intermediary element enables the application of controlled shear forces without requiring the extreme lateral displacements needed in traditional hard shear methods, thus achieving alignment compatible with high-speed production.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If soft shear orientation is applied by swelling/deswelling of PDMS pads, then alignment is achieved, but the process requires minutes to hours and is not scalable

Engineering Contradiction:
ImprovealignmentVSAvoidorientation time
Core Design Contradiction:
Manufacturing precisionVSDuration of action of moving object

Solution Approach 1:

The patent replaces the chemical/swelling-based soft shear mechanism with a direct mechanical shear application. Instead of relying on PDMS pad swelling and deswelling that requires extended time, the flexible blade applies mechanical shear forces directly to the film during coating, achieving alignment in seconds rather than minutes or hours and enabling scalable production.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the key parameter from time-dependent swelling/deswelling to speed-dependent shear application. By controlling the relative motion between the flexible blade and substrate during coating, the system achieves alignment based on coating speed rather than prolonged exposure time, reducing orientation time from minutes/hours to seconds and enabling high-throughput production.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If two separate steps for casting and shear alignment are used, then each step can be optimized, but device complexity and process difficulty increase

Engineering Contradiction:
Improveprocess optimizationVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges the coating device and flexible blade into a single integrated coating head assembly. This unified structure allows both film deposition and shear alignment functions to be performed within one device, reducing the number of separate components, simplifying the overall process flow, and eliminating the need for multiple device setups while maintaining the ability to optimize both functions simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the speed of shear alignment by 2-4 orders of magnitude, enabling high-throughput roll-to-roll processing of hierarchical materials without causing film damage, and produces highly ordered nanostructures suitable for advanced nanotechnology applications.

Implementation Method 1

A coating head with a flexible blade that applies shear force during film drying, combining the benefits of 'hard' and 'soft' shear techniques in a single continuous process, allowing for simultaneous film casting and directional alignment of nanostructures

Methodology Applied
Scientific EffectShear force: Shear Stress

Implementation Method 2

the coating device and the first flexible blade are separated by a spacing distance such that partial loss of solvent occurs from a starting film formed on the substrate by the coating device as the coating head is drawn over the substrate, the partial solvent loss forming the solvent-containing film

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS10828664B2Device and method for making shear-aligned, solvent-cast films
Publication Date: 2020.11.10 UNIVERSITY OF DELAWARE
  • US10828664B2 patent drawing
  • US10828664B2 patent drawing
  • US10828664B2 patent drawing

AI summary

A coating head includes a coating device and at least a first flexible blade that is capable of being shaped into contact with a solvent-containing film on a substrate upon pressing the first flexible blade against the film, thereby providing contact between the blade and the film over a contact distance when the coating head is drawn over the substrate. The coating device and the blade are separated by a spacing distance such that partial loss of solvent occurs from a starting film formed on the substrate by the coating device as the coating head is drawn over the substrate, the partial solvent loss forming the solvent-containing film. A method of producing a film having a hierarchical structure includes drawing a coating head across a substrate to form on the substrate via the coating device a starting film including a solvent and a material for forming the hierarchical structure.