Flexible Carbon Electrode Structure for Crack-Resistant Bending

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Solution Overview

Problem

Existing electrodes with carbon thin films are prone to cracking when curved, leading to increased resistance due to their brittleness.

Innovation Solution

An electrode comprising a resin film, a metal underlying layer, and a conductive carbon layer with sp3 bonds, where the conductive carbon layer has a density of 1.8 g/cm3 or more and a thermal shrinkage of −0.2% or less when heated at 150°C for 1 hour, suppressing damage and resistance increase upon curvature.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If the electrode is curved to adapt to different uses, then the adaptability is improved, but the carbon thin film is easily cracked due to brittleness, causing resistance to increase

Engineering Contradiction:
ImproveadaptabilityVSAvoidresistance stability
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the bonding structure parameter of the carbon thin film from primarily sp2 bonds to a composite structure with sp3 bonds (ratio of sp3 to total bonds: 0.05 or more). This parameter change transforms the carbon film from brittle to flexible while maintaining conductivity, enabling the electrode to be curved without cracking and resistance increase.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If the carbon thin film is made more flexible to prevent cracking, then the ease of operation is improved, but the conductivity may be compromised

Engineering Contradiction:
ImproveflexibilityVSAvoidconductivity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent creates a composite carbon structure containing both sp2 bonds (providing conductivity) and sp3 bonds (providing flexibility). The specific composition (sp3 bond ratio ≥ 0.05) optimizes the balance between flexibility and conductivity, allowing the carbon film to bend without cracking while maintaining electrical performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The electrode effectively prevents damage to the conductive carbon layer and minimizes the rate of resistance increase even when curved, maintaining electrical conductivity and sensitivity.

Implementation Method 1

a thermal shrinkage of the electrode is −0.2% or more and 0.2% or less when the electrode is heated at 150° C. for 1 hour

Methodology Applied
Scientific EffectThermal shrinkage: Thermal Contraction

Data Source

PatentUS20240167976A1electrode
Publication Date: 2024.05.23 NITTO DENKO CORP
  • US20240167976A1 patent drawing
  • US20240167976A1 patent drawing
  • US20240167976A1 patent drawing

AI summary

An electrode includes a resin film and a conductive carbon layer in this order in a thickness direction. The conductive carbon layer has an sp3 bond. The electrode has a thermal shrinkage of −0.2% or more and 0.2% or less when being heated at 150° C. for 1 hour.