Flexible Cement Slurry for Zonal Isolation

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Solution Overview

Problem

Existing cement systems for subterranean wells face challenges in maintaining effective zonal isolation due to poor bonding and mechanical integrity issues caused by pressure fluctuations, temperature changes, and mechanical disturbances, which can lead to reduced production and ineffective stimulation treatments.

Innovation Solution

A flexible cement composition with a solid volume fraction between 0.30 and 0.40, comprising an inorganic cement and at least one mineral, is developed, which includes a blend of coarse, medium-size, and fine particles, and microsilica or silica fume to enhance flexibility and reduce permeability, while maintaining a water-to-cement ratio between 0.7 and 1.5 by weight, and using specific minerals like metallic iron, metal oxides, and carbonates to achieve optimal mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If cement slurry with higher solid volume fraction is used to improve zonal isolation, then permeability decreases and isolation improves, but the slurry becomes more difficult to pump and place into the well

Engineering Contradiction:
Improvezonal isolationVSAvoidslurry placement
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent optimizes the solid volume fraction parameter to a specific range (0.44-0.48) that balances permeability reduction for zonal isolation with maintainable pumpability for slurry placement. This parameter optimization resolves the contradiction by finding the optimal point where both isolation effectiveness and operational ease are satisfied.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite cement slurry formulation containing multiple components including cement, water, and various additives in specific proportions. This composite approach allows the slurry to achieve both low permeability (for isolation) and appropriate rheology (for pumpability) by combining materials with complementary properties.

Inventive Principle:
Principle #40Composite materials

2Strength

If cement systems with flexible additives like elastomer particles are used to improve flexibility and toughness, then resistance to mechanical disturbances improves, but the solid volume fraction decreases and permeability increases

Engineering Contradiction:
ImprovetoughnessVSAvoidzonal isolation
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent carefully controls the solid volume fraction within the narrow range of 0.44-0.48, which allows sufficient space for flexible additives like elastomer particles to improve toughness while maintaining enough solid content to ensure low permeability and effective zonal isolation. This precise parameter control resolves the contradiction between toughness and isolation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cement system that integrates elastomer particles and other flexible additives within the cement matrix. This composite structure provides both the flexibility/toughness needed to resist mechanical disturbances and the dense enough packing to maintain low permeability for zonal isolation.

Inventive Principle:
Principle #40Composite materials

3Strength

If fibers are added to cement to provide mechanical reinforcement, then tensile strength improves, but the slurry viscosity increases and placement becomes more difficult

Engineering Contradiction:
Improvetensile strengthVSAvoidslurry placement
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent optimizes the solid volume fraction and water-to-cement ratio to specific ranges that accommodate fiber reinforcement while maintaining acceptable slurry viscosity for placement. By controlling these parameters, the patent ensures that fibers provide tensile strength enhancement without causing excessive viscosity increase that would hinder pumpability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved mechanical properties, such as Young's modulus between 1.0 GPa and 6.0 GPa, and maintains permeability below 0.1 mD, ensuring effective zonal isolation and resistance to mechanical disturbances, while preventing particle sedimentation and enhancing fluid-loss control.

Implementation Method 1

The set cement provides zonal isolation, which is the prevention of fluid flow between different formation layers

Methodology Applied
Scientific EffectCement hydration: Chemical Bonding

Implementation Method 2

Many of the improved cement systems may contain flexible additives, including elastomer particles

Methodology Applied
Scientific EffectElasticity: Elasticity

Implementation Method 3

a blend comprising an inorganic cement and at least one mineral... a blend of coarse, medium-size, and fine particles

Methodology Applied
Scientific EffectParticle packing: Close Packing

Implementation Method 4

maintains permeability below 0.1 mD, ensuring effective zonal isolation

Methodology Applied
Scientific EffectPorosity reduction: Porosity

Data Source

PatentEP2966143B1Methods for well cementing
Publication Date: 2019.08.21 SERVICES PETROLIERS SCHLUMBERGER SA

AI summary

Cement slurries are prepared that comprise water and a blend comprising an inorganic cement and at least one mineral. The slurries may have a solid volume fraction between 0.3 and 0.4, and the cement may be present at concentrations between 30% and 70% by volume of blend. The slurries may be placed in a subterranean well and allowed to harden and form set cements.