Flexible Thermoplastic Resin Light Guide with Anti-Yellowing Clad

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Solution Overview

Problem

Conventional light guiding rods made from transparent resins are too rigid for practical use due to high flexural modulus of elasticity, limiting their ability to be bent for decorative purposes, and they suffer from luminescent color yellowing at distances away from the light source.

Innovation Solution

A thermoplastic resin molded body with a core layer made from acryl-based thermoplastic elastomer and a clad layer with added light diffusing agents, where the total light transmittance of the clad layer is less than 70%, and a second clad layer without diffusing agents is interposed between the core and first clad layers, along with a bluing agent to prevent color yellowing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a transparent resin with high flexural modulus of elasticity is used for the core layer, then the light guiding rod maintains structural integrity, but it becomes too rigid to be bent for practical decorative use

Engineering Contradiction:
Improvestructural integrityVSAvoidflexibility for bending
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent changes the material parameter of the core layer from conventional transparent resins to thermoplastic elastomers, which have different mechanical properties including lower flexural modulus of elasticity, enabling flexibility while maintaining light guiding functionality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite structure with a core layer made of thermoplastic elastomer and a clad layer made of transparent resin, combining the flexibility of the elastomer core with the optical clarity and strength of the resin clad to achieve both bendability and structural integrity

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If an acryl based thermoplastic elastomer is used for the core layer to achieve flexibility, then the rod can be bent, but the light emitting performance is insufficient and luminescent color yellowing occurs at distal locations

Engineering Contradiction:
Improveflexibility for bendingVSAvoidlight emitting performance
Core Design Contradiction:
Adaptability or versatilityVSIllumination intensity

Solution Approach 1:

The patent applies different properties to different parts of the light guiding rod: the core layer contains a light diffusing agent for uniform light distribution, the clad layer has specific refractive index properties for light guidance, and a bluing agent is added to counteract yellowing, with each layer optimized for its specific function

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces a light diffusing agent as an intermediary substance in the core layer to scatter and distribute light uniformly, and a bluing agent as another intermediary to optically compensate for yellowing, thereby improving light emitting performance without sacrificing flexibility

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If a small amount of bluing agent is added to suppress yellowing, then the luminescent color remains stable, but the overall light transmittance and luminance are reduced

Engineering Contradiction:
Improvechromaticity stabilityVSAvoidoverall luminance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent optimizes the concentration parameter of the bluing agent within a specific range (0.01-10 ppm) to achieve the minimum effective amount for suppressing yellowing while minimizing the negative impact on light transmittance and overall luminance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution allows for a flexible light guiding rod that can be bent and formed into decorative shapes, improving light emitting performance and preventing luminescent color yellowing, enhancing its industrial applicability.

Implementation Method 1

a light diffusing agent is added to the thermoplastic elastomer from which the core layer 1 is made and the thermoplastic resin from which the first clad layer 2 is made respectively

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

a first clad layer 2 made from a thermoplastic resin whose refractive index is smaller than that of the thermoplastic elastomer from which the core layer is made

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 3

a small amount of bluing agent being added to the resin materials from which the core layer and the clad layer are made so as to make the light emitted from such rod somewhat bluish

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Data Source

PatentEP3605170B1Thermoplastic resin molding of peripheral surface light-emitting type
Publication Date: 2022.12.28 KURARAY CO LTD
  • EP3605170B1 patent drawingFigure 1~2
  • EP3605170B1 patent drawingFigure 3
  • EP3605170B1 patent drawingFigure 4

AI summary

To provide a circumferentially light-emitting type thermoplastic resin molded body which can be flexibly bent for use according to the type of optical ornaments or the shape of an object to be decorated and which allows the overall luminance of the emitted light to improve and restrains the luminescent color from being yellowed at the distal locations of such body with regard to the light source. The thermoplastic resin molded body at least comprises a core layer 1 made from a thermoplastic elastomer; and a first clad layer 2 made from a thermoplastic resin whose refractive index is smaller than that of the thermoplastic elastomer from which the core layer 1 is made, in which a light diffusing agent is added to the thermoplastic elastomer from which the core layer (1) is made and the thermoplastic resin from which the first clad layer (2) is made respectively; and the total light transmittance of the first clad layer 2 is defined as less than 70%.