Flexible Mid-IR Waveguide for Chemical Sensing

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Solution Overview

Problem

Current flexible photonics platforms are unsuitable for chemical sensing applications due to their opacity in the mid-IR wavelength range and degradation under harsh environmental conditions, limiting their portability and effectiveness.

Innovation Solution

A flexible waveguide structure using aluminum nitride as the waveguide material and a borosilicate substrate with a mid-IR-transparent undercladding, allowing for mid-IR transparency and flexibility, enabling chemical sensing applications with enhanced mechanical and thermal resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If flexible polymer substrates are used for photonics, then flexibility and portability are improved, but mid-IR transparency is lost due to opacity in the mid-IR wavelength range

Engineering Contradiction:
ImproveflexibilityVSAvoidopacity in mid-IR range
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent employs a composite structure consisting of a flexible polymer substrate combined with mid-IR transparent materials (such as silicon oxide or silicon nitride waveguides). This composite approach allows the device to maintain flexibility from the polymer substrate while achieving mid-IR transparency through the transparent material layers, thereby resolving the contradiction between flexibility and mid-IR transparency.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If flexible polymer substrates are used, then portability is improved, but reliability deteriorates due to decomposition under high temperature and degradation when exposed to organic solvents

Engineering Contradiction:
ImproveportabilityVSAvoidstability under harsh conditions
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent uses a composite structure where the flexible polymer substrate is combined with environmentally stable materials such as silicon oxide or silicon nitride. These inorganic materials provide resistance to high temperature and organic solvents, while the polymer substrate maintains flexibility and portability. This composite approach resolves the contradiction between portability and reliability under harsh conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs thin film structures of mid-IR transparent materials deposited on flexible substrates. These thin films provide environmental stability while maintaining the flexibility of the underlying substrate, enabling portable devices that can withstand harsh conditions.

Inventive Principle:
Principle #30Flexible shells and thin films

3Object-affected harmful factors

If standard rigid photonic material platforms are used, then mid-IR transparency is improved, but flexibility is lost

Engineering Contradiction:
Improvemid-IR transparencyVSAvoidflexibility
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent combines rigid mid-IR transparent materials (silicon oxide, silicon nitride) with flexible polymer substrates to create a composite structure. The rigid material layers provide mid-IR transparency, while the flexible substrate provides bendability, resolving the contradiction between transparency and flexibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent uses thin film structures of transparent materials that can be deposited on flexible substrates. These thin films maintain mid-IR transparency while allowing the overall structure to be flexible and bendable, enabling portable photonic devices.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a portable, wearable, and robust chemical sensing platform capable of operating in harsh environments with accurate chemical identification and concentration monitoring, leveraging mid-IR transparency and nonlinear optical properties for efficient sensing.

Implementation Method 1

aluminum nitride as the waveguide material and a borosilicate substrate with a mid-IR-transparent undercladding, allowing for mid-IR transparency

Methodology Applied
Scientific EffectMid-IR transparency: Absorption (EM radiation)

Implementation Method 2

Infrared (IR) spectroscopy is routinely used for material identification and characterization. Numerous chemical functional groups have characteristic absorption bands and absorption patterns (called 'fingerprints') in the IR spectrum

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Data Source

PatentUS10591410B2Flexible mid-infrared photonics for chemical sensing
Publication Date: 2020.03.17 TEXAS A&M UNIVERSITY
  • US10591410B2 patent drawing
  • US10591410B2 patent drawing
  • US10591410B2 patent drawing

AI summary

A flexible waveguide structure including a waveguide on a flexible substrate, both having transparent windows in the mid-infrared range, may serve as a photonic chemical sensor for measuring characteristic absorptions of analytes brought in physical contact with the waveguide. Such a sensor may, in accordance with some embodiments, be formed by an aluminum-nitride waveguide on a borosilicate substrate.