Flexible OLED Barrier Layers for Moisture Resistance

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Solution Overview

Problem

Flexible organic light-emitting display apparatuses with plastic substrates face challenges due to high moisture and oxygen transmission rates, leading to degradation and limited durability, and existing barrier layers often suffer from delamination issues due to weak adhesive strength.

Innovation Solution

The use of a flexible substrate with a first and second plastic layer, each paired with a patterned and continuous inorganic barrier layer, respectively, to create a longer water vapor transmission path and enhance adhesive strength, thereby preventing moisture and oxygen penetration and delamination.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If a flexible plastic substrate is used instead of glass substrate, then portability and flexibility are improved, but moisture and oxygen transmission increases leading to degradation

Engineering Contradiction:
ImproveflexibilityVSAvoidmoisture resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent employs a composite barrier layer structure combining organic and inorganic materials. The barrier layer includes an organic layer (first or second plastic layer) and an inorganic layer (first or second inorganic barrier layer) stacked together, creating a composite structure that leverages the flexibility of organic materials while providing the moisture and oxygen barrier properties of inorganic materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements a nested multi-layer barrier structure where multiple barrier layers are stacked sequentially. The first plastic layer and first inorganic barrier layer form an first barrier structure, while the second plastic layer and second inorganic barrier layer form a second barrier structure. These nested layers create a complex transmission path that effectively blocks moisture and oxygen while maintaining flexibility.

Inventive Principle:
Principle #7Nested doll (Nesting)

2Weight of moving object

If a flexible plastic substrate is used instead of glass substrate, then portability is improved, but durability decreases due to degradation

Engineering Contradiction:
ImproveweightVSAvoiddurability
Core Design Contradiction:
Weight of moving objectVSDuration of action of stationary object

Solution Approach 1:

The composite barrier layer structure combining organic and inorganic materials provides both weight reduction (from flexible plastic substrate) and enhanced durability (from the protective barrier against moisture and oxygen). The inorganic barrier layers prevent degradation while the organic layers maintain flexibility and light weight.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The barrier layers are applied beforehand to the flexible substrate to prevent future degradation. The first and second inorganic barrier layers are deposited on the plastic layers before the organic light-emitting layer is formed, creating a protective cushion against moisture and oxygen that prevents degradation before it can occur.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Reliability

If a barrier layer is added to prevent moisture transmission, then moisture resistance is improved, but adhesive strength decreases causing delamination

Engineering Contradiction:
Improvemoisture resistanceVSAvoidadhesive strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The composite structure of organic and inorganic layers in the barrier layer creates interfacial bonding between layers with different adhesive properties. The organic layer provides good adhesive strength to the plastic substrate, while the inorganic layer provides the moisture barrier, and their interface creates a composite structure that maintains both adhesion and barrier performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different materials with different properties at different locations in the barrier structure. The organic layers are positioned where adhesive bonding is critical (interface with plastic substrate), while inorganic layers are positioned where moisture blocking is most effective. This local optimization of material properties resolves the contradiction between adhesion and barrier performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly reduces the degradation of organic light-emitting layers by minimizing water vapor transmission and preventing delamination between barrier and plastic layers, leading to improved durability and reliability of the organic light-emitting display apparatus.

Implementation Method 1

a first barrier layer formed over the first flexible plastic layer, the first barrier layer being substantially impervious to water and oxygen

Methodology Applied
Scientific EffectPermeation barrier:

Implementation Method 2

The first barrier layer is patterned to correspond to an area where the organic light-emitting device layer is formed

Methodology Applied
Scientific EffectDiffusion path extension: Diffusion

Implementation Method 3

The organic light-emitting display apparatus is a self light-emitting display apparatus that emits light when holes injected from the hole injection electrode and electrons injected from the electron injection electrode recombine within the organic light-emitting layer giving rise to an excited state that gradually dissipates thereafter

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP2806473B1Organic Light-Emitting Display Apparatus Having a Flexible Substrate
Publication Date: 2020.05.06 SAMSUNG DISPLAY CO LTD
  • EP2806473B1 patent drawingFigure 1~2
  • EP2806473B1 patent drawingFigure 3~4
  • EP2806473B1 patent drawingFigure 5A~5B

AI summary

An organic light-emitting display apparatus includes a flexible substrate (FS). The organic light-emitting display apparatus includes a first plastic layer (1PL). A first barrier layer (1BL) is formed on the first plastic layer. A second plastic layer (2PL) is formed on the first barrier layer. An organic light-emitting device layer (120) is formed on the second plastic layer. A thin film encapsulating layer (130) encapsulates the organic light-emitting device layer. The first barrier layer (1BL) is patterned to correspond to an area where the organic light-emitting device layer (120) is formed.