Flexible OLED Encapsulation with Nitrogen-Doped Silicon Oxide

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Solution Overview

Problem

Flexible OLED devices face damage and display quality degradation due to moisture penetration and incomplete coverage of the encapsulating film, leading to cracks and reduced flexibility under high temperature and humidity conditions.

Innovation Solution

A flexible OLED device with an encapsulation film featuring a first inorganic layer formed by atomic layer deposition (ALD) and an organic layer, where the upper region of the inorganic layer includes nitrogen-doped silicon oxide to enhance surface energy and improve step-coverage, and a second inorganic layer is formed by plasma-enhanced chemical vapor deposition (PECVD) to prevent moisture penetration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If an encapsulation film with inorganic and organic layers is used instead of a glass substrate, then the device achieves flexibility, but the emitting diode remains susceptible to moisture penetration and damage under high temperature and humidity conditions

Engineering Contradiction:
ImproveflexibilityVSAvoidprotection against moisture penetration
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The inorganic layer is modified with nitrogen doping specifically in the upper region to enhance surface energy and improve step-coverage, creating local quality enhancement where it is most needed for moisture barrier performance while maintaining overall encapsulation integrity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the chemical composition parameter of the inorganic layer by introducing nitrogen doping, which fundamentally alters the surface properties and moisture barrier characteristics of the encapsulation film, enabling it to effectively prevent moisture penetration while maintaining flexibility

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If the encapsulation film is made thinner to maintain flexibility, then the device maintains its flexible property, but the coverage completeness and protection against particles decrease

Engineering Contradiction:
Improveflexible propertyVSAvoidcoverage completeness
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

Nitrogen doping is applied specifically to the upper region of the inorganic layer to enhance step-coverage and surface energy, ensuring complete coverage of particles and steps even in thinner encapsulation structures, thereby maintaining manufacturing precision while preserving flexibility

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

By modifying the surface energy parameter through nitrogen doping, the encapsulation film achieves improved wetting and coverage characteristics that enable complete particle coverage even when the overall film thickness is reduced to maintain flexibility

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If a traditional encapsulation structure is used, then the device structure is simple, but stress concentration occurs leading to cracks and display quality degradation

Engineering Contradiction:
Improveencapsulation structure simplicityVSAvoidresistance to stress and cracks
Core Design Contradiction:
Device complexityVSStrength

Solution Approach 1:

The encapsulation structure maintains its simple layered configuration but introduces nitrogen doping in the upper region of the inorganic layer to locally enhance mechanical strength and stress distribution, preventing crack formation without increasing overall structural complexity

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the material composition parameter of the inorganic layer through nitrogen doping, which fundamentally alters the mechanical properties and stress resistance of the encapsulation film, enabling it to withstand stress without cracking while maintaining structural simplicity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents damage to the organic emitting diode by ensuring complete coverage of particles and reducing stress on the encapsulation film, maintaining display quality and extending the device's lifetime without increasing thickness.

Implementation Method 1

the upper region of the first inorganic layer includes a first nitrogen-doped silicon oxide

Methodology Applied
Scientific EffectNitrogen doping: Dopants

Implementation Method 2

an encapsulation film covering the organic emitting diode and including a first inorganic layer and an organic layer, wherein an upper region of the first inorganic layer includes a first nitrogen-doped silicon oxide

Methodology Applied
Scientific EffectAtomic layer deposition: Physical Vapour Deposition

Implementation Method 3

a second inorganic layer is formed by plasma-enhanced chemical vapor deposition (PECVD) to prevent moisture penetration

Methodology Applied
Scientific EffectPlasma-enhanced chemical vapor deposition: Plasma Enhanced Chemical Vapour Deposition

Data Source

PatentUS10468626B2Flexible organic light emitting display device and method of fabricating the same
Publication Date: 2019.11.05 LG DISPLAY CO LTD
  • US10468626B2 patent drawing
  • US10468626B2 patent drawing
  • US10468626B2 patent drawing

AI summary

A flexible organic light emitting display (OLED) device includes an organic emitting diode on a flexible substrate, an encapsulation film covering the organic emitting diode and including a first inorganic layer and an organic layer. The first inorganic layer is formed of a first material, and at least a portion of the first inorganic layer includes a dopant that increases the surface energy of the doped material compared to that of non-doped material.