Flexible Sensor Manufacturing via CNT Bridging and Electric Field Alignment

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Solution Overview

Problem

The existing dry-blended method for manufacturing flexible sensors using graphene or carbon nanotubes results in a significant reduction in electrical and piezoresistive properties compared to solvent-based methods, and it lacks biocompatibility due to the use of toxic organic solvents.

Innovation Solution

A method that involves dispersing graphene in a polymeric material using mechanical stirring and high-power ultrasound, adding carbon nanotubes, applying an alternating electric field, and embedding carbon fibers to enhance the electrical conductivity, piezoresistive properties, and mechanical properties of the polymeric material, while avoiding toxic solvents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a non-toxic dry-blended method is used to manufacture flexible sensors, then toxic solvent residue is eliminated and biocompatibility is improved, but electrical conductivity and piezoresistive properties are significantly reduced

Engineering Contradiction:
Improvetoxic solvent residueVSAvoidelectrical conductivity
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Carbon nanotubes serve as an intermediary substance that bridges the gap between graphene clusters in the polymeric material. The carbon nanotubes act as conductive pathways that restore electrical conductivity while maintaining the non-toxic dry-blended preparation method. This intermediary approach allows the system to achieve both biocompatibility and electrical functionality.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system combining graphene, carbon nanotubes, and polymeric materials (such as PDMS or PMMA). This composite structure leverages the high conductivity of graphene, the bridging capability of carbon nanotubes, and the biocompatible properties of the polymer matrix to achieve both electrical performance and biocompatibility simultaneously.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If a non-toxic dry-blended method is used to manufacture flexible sensors, then toxic solvent residue is eliminated and biocompatibility is improved, but piezoresistive properties are significantly reduced

Engineering Contradiction:
Improvetoxic solvent residueVSAvoidpiezoresistive property
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Carbon nanotubes function as an intermediary that enhances piezoresistive properties by providing additional conductive pathways that respond to mechanical deformation. When the polymeric material is stretched or deformed, the carbon nanotube network undergoes changes in resistance that amplify the piezoresistive effect, compensating for the limitations of the dry-blended method.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The composite material system combines the piezoresistive characteristics of graphene with the mechanical flexibility and conductive network formation capabilities of carbon nanotubes within a biocompatible polymeric matrix, achieving enhanced piezoresistive properties without toxic solvents.

Inventive Principle:
Principle #40Composite materials

3Reliability

If carbon nanotubes are added to polymeric material to improve electrical conductivity, then electrical conductivity is enhanced, but device complexity increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the functions of conductivity enhancement and mechanical reinforcement into a single additive material - carbon nanotubes. This consolidation allows both electrical conductivity improvement and structural enhancement to be achieved through one material addition, simplifying the overall formulation process compared to using multiple separate additives.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent optimizes the concentration and aspect ratio of carbon nanotubes as key parameters to achieve effective conductivity enhancement at low additive levels. By carefully controlling these parameters, the system achieves good electrical performance while minimizing the complexity of material formulation and processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The improved method significantly enhances the electrical conductivity, piezoresistive strain range, and mechanical properties of the flexible sensor, and demonstrates improved biocompatibility by reducing toxic residue and improving cell survival and function.

Implementation Method 1

a CNT bridging effect is introduced at an appropriate ratio of polymeric materials such as graphene-PDMS or PMMA to improve a dry-blended method

Methodology Applied
Scientific EffectCNT bridging effect:

Implementation Method 2

an electric field induced arrangement is introduced at an appropriate ratio of polymeric materials such as graphene-PDMS or PMMA

Methodology Applied
Scientific EffectElectric field induced arrangement: Electric Field

Implementation Method 3

dispersing graphene in a polymeric material in a mode of mechanical stirring and high-power ultrasound

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS20230340225A1Method for manufacturing flexible sensor
Publication Date: 2023.10.26 QILU UNIVERSITY OF TECHNOLOGY (SHANDONG ACADEMY OF SCIENCES)
  • US20230340225A1 patent drawing
  • US20230340225A1 patent drawing
  • US20230340225A1 patent drawing

AI summary

A method for manufacturing a flexible sensor, including: dispersing graphene in a polymeric material; adding a carbon nanotube into the polymeric material; applying an alternating electric field to the polymeric material added with the carbon nanotube to obtain a composite material; attaching a polymeric material film to the obtained composite material; pre-embedding carbon fibers; and heating and curing to obtain a sensor. A CNT bridging effect and an electric field induced arrangement are introduced at an appropriate ratio of polymeric materials such as graphene-PDMS or PMMA to improve a dry-blended method. The flexible sensor manufactured by the improved dry-blended method improves electrical conductivity, a piezoresistive property and a mechanical property of CNT-graphene-PDMS or PMMA and other polymeric materials.