Flexible Thermal Protection Material Fabrication

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Solution Overview

Problem

Existing thermal protection systems (TPS) for atmospheric entry vehicles face challenges with brittleness, low strain-to-failure, and high thermal conductivity due to their rigid nature, which limits their flexibility and mechanical toughness, and requires extensive gap filling and structural support, increasing weight and complexity.

Innovation Solution

Development of a low-density flexible TPS material comprising a flexible carbon fiber substrate impregnated with a pyrolizable thermoset resin, such as phenolic or polyimide, which remains flexible after pyrolysis, offering improved mechanical and thermal properties, including high strain-to-failure and reduced thermal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If rigid refractory-fiber tile insulation is used to limit heat conduction, then thermal insulation performance is improved, but weight and structural complexity increase

Engineering Contradiction:
Improvethermal insulation performanceVSAvoidTPS weight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent changes the physical state and mechanical properties of the ablator material by using a flexible fabric substrate instead of rigid tiles, while maintaining the ablative function. The flexible material achieves comparable thermal protection with reduced thickness and weight by utilizing the fabric's inherent flexibility to conform to the vehicle surface without requiring thick rigid sections.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite structure consisting of a flexible fabric substrate (such as carbon fiber or ceramic fiber fabric) impregnated with ablative polymer material. This composite combines the thermal protection capabilities of traditional ablators with the weight and flexibility advantages of fabric structures, eliminating the need for heavy rigid support.

Inventive Principle:
Principle #40Composite materials

2Reliability

If rigid refractory-fiber tiles are used for thermal protection, then heat conduction is reduced, but device complexity increases due to gap fillers and support structures

Engineering Contradiction:
Improvethermal protection effectivenessVSAvoidTPS structural complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses a flexible fabric-based ablator that can conform to curved surfaces and accommodate thermal expansion without requiring rigid support structures or gap fillers. The flexible nature of the material allows it to be applied as a continuous covering that simplifies the overall TPS structure by eliminating multiple discrete components and their associated fastening and sealing systems.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If traditional ablative materials are used, then thermal protection is provided through ablation, but brittleness and low strain-to-failure limit flexibility

Engineering Contradiction:
Improvethermal protection mechanismVSAvoidstrain-to-failure
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent employs a flexible fabric substrate (such as woven carbon fiber, ceramic fiber, or organic fiber fabric) as the structural backbone of the ablator. This fabric structure provides the necessary flexibility and strain-to-failure characteristics while the impregnated ablative material maintains the thermal protection function. The fabric can undergo significant deformation without fracture, enabling the TPS to accommodate vehicle flexing and thermal expansion.

Inventive Principle:
Principle #30Flexible shells and thin films

4Reliability

If thick insulation is used to minimize heat conduction, then thermal resistance is improved, but mass and thickness penalties increase

Engineering Contradiction:
Improvethermal resistanceVSAvoidinsulation thickness
Core Design Contradiction:
ReliabilityVSLength of moving object

Solution Approach 1:

The patent optimizes the thickness and density parameters of the ablator material by using a flexible fabric structure that provides effective thermal protection in a thinner profile. The fabric's three-dimensional structure and the impregnated material create a thermal barrier that is more efficient per unit thickness than traditional rigid tiles, reducing the overall insulation thickness required while maintaining thermal resistance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The flexible TPS material retains its mechanical properties and flexibility after charring, providing enhanced toughness, reduced thermal conductivity, and the ability to be applied in large sections without gap fillers, thus reducing weight and complexity while maintaining effective thermal protection.

Implementation Method 1

Ablation causes some of the TPS material to char and sublime through the process of pyrolysis

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

The gas produced by pyrolysis blocks convective heat flux

Methodology Applied
Scientific EffectConvection blocking: Convection

Implementation Method 3

Ablation can also provide blockage against radiative heat flux by introducing carbon particulates into the boundary layer to make it optically opaque

Methodology Applied
Scientific EffectRadiation blocking: Radiation

Implementation Method 4

thermal insulation against conductive heat flow from an outer surface to an inner surface is still critical

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentUS10427807B1Method of fabricating a flexible, low-density thermal protection material
Publication Date: 2019.10.01 UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR NAT AERONAUTICS & SPACE ADMINISTRATION
  • US10427807B1 patent drawing
  • US10427807B1 patent drawing
  • US10427807B1 patent drawing

AI summary

A method for preparing a flexible low-density thermal protection material, the method comprising providing a flexible substrate and a pyrolizable material impregnated therein. The thermal protection material remains flexible after impregnation and continues to remain flexible when the pyrolizable material is fully pyrolized.