Thermal Post-Treated Coke Proppants for Stronger Fracture Conductivity

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Solution Overview

Problem

Existing proppants used in hydraulic fracturing, such as sand, suffer from high cost and limited hydrocarbon recovery rates, necessitating the development of high-performance proppants and fracturing fluids.

Innovation Solution

The use of thermally post-treated fluid coke and flexicoke proppant particles, treated at temperatures between 400°C to 1200°C for durations ranging from 1 minute to 24 hours, which are then mixed with a carrier fluid and optionally other additives, to enhance mechanical properties and improve fracture conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional sand proppant is used in hydraulic fracturing, then the fracture conductivity is maintained, but the cost is high and hydrocarbon recovery rate is limited

Engineering Contradiction:
Improvehydrocarbon recovery rateVSAvoidcost
Core Design Contradiction:
ProductivityVSQuantity of substance

Solution Approach 1:

The invention applies parameter changes by thermally treating coke particles at temperatures between 400°C to 1200°C for durations of 1 minute to 24 hours. This thermal treatment modifies the physical and chemical properties of the coke proppant, enhancing its mechanical strength and fracture conductivity characteristics, thereby improving hydrocarbon recovery while using a cost-effective material

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining coke particles with optional additives and carrier fluids to create a enhanced proppant system. The coke-based proppant can be mixed with other materials to optimize performance characteristics, achieving both cost-effectiveness and high productivity

Inventive Principle:
Principle #40Composite materials

2Strength

If thermally post-treated fluid coke and flexicoke proppant particles are used, then strength and conductivity are improved, but the treatment process complexity increases

Engineering Contradiction:
Improveproppant strengthVSAvoidthermal treatment process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The thermal treatment process applies controlled parameter changes (temperature and time) to transform the coke particles into high-strength proppant. By systematically varying temperature (400°C to 1200°C) and duration (1 minute to 24 hours), the process achieves desired strength and conductivity improvements through well-understood thermal transformation mechanisms

Inventive Principle:
Principle #35Parameter changes

3Reliability

If thermally post-treated fluid coke and flexicoke proppant particles are used, then fracture conductivity is improved, but the treatment time and energy consumption increase

Engineering Contradiction:
Improvefracture conductivityVSAvoidtreatment duration
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The invention uses parameter changes to optimize the thermal treatment process, allowing flexibility in balancing treatment time and energy consumption against the achieved fracture conductivity. Higher temperatures can achieve the desired properties in shorter times, while lower temperatures require longer durations, enabling process optimization based on specific application requirements

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The thermally treated proppant particles demonstrate improved strength and conductivity, enabling more effective propping of fractures and enhancing hydrocarbon production by maintaining high hydraulic conductivities under stress conditions.

Implementation Method 1

The thermally post-treated fluid coke and/or flexicoke proppant particles are produced by heat-treating the fluid coke and/or flexicoke particles, respectively, to a temperature in a range from 400° C. to 1200° C. for a predetermined duration that is in range from 1 minute to 24 hours

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS12540273B2Proppant particles formed from fluid coke and flexicoke, fracturing fluids comprising such proppant particles, and methods related thereto
Publication Date: 2026.02.03 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US12540273B2 patent drawing
  • US12540273B2 patent drawing
  • US12540273B2 patent drawing

AI summary

A fracturing fluid comprises a carrier fluid and thermally post-treated fluid coke and/or flexicoke proppant particles, comprising fluid coke and/or flexicoke particles, respectively, that have been thermally post-treated to a temperature in a range from 400° C. to 1200° C. for a predetermined duration. A method of utilizing such fracturing fluid comprises introducing the fracturing fluid into a subterranean formation. A method of making such fracturing fluid comprises producing the thermally post-treated fluid coke and/or flexicoke proppant particles by thermally post-treating the fluid coke and/or flexicoke particles, respectively, to the temperature in the range from 400° C. to 1200° C. for the predetermined duration and mixing the thermally post-treated fluid coke and/or flexicoke proppant particles with the carrier fluid, optionally along with one or more other types of proppant particles and/or one or more additives.