High-Resolution Flexographic Printing Plate Interlayer Composite

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Solution Overview

Problem

Conventional flexographic printing plates face challenges in achieving high-resolution reproduction of fine printing elements and tonal values, particularly in the range of 0-5% and 95-100%, due to limitations in the intermediate layer thickness, oxygen attack during exposure, and stability issues with existing recordable layers.

Innovation Solution

A recording element with an interlayer composite consisting of two polymer-containing layers, where a barrier layer prevents diffusion and oxygen penetration, and an adhesion-modulating layer facilitates easy removal of the recordable template layer, enhancing resolution and stability without requiring additional protective atmospheres.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a thin intermediate layer is used to improve resolution, then halftone dot resolution is improved, but the layer becomes unstable and ages quickly

Engineering Contradiction:
Improvehalftone dot resolutionVSAvoidlayer stability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The intermediate layer is divided into two separate layers: a first intermediate layer in direct contact with the recordable template layer and a second intermediate layer in direct contact with the relief layer. This segmentation allows each layer to have optimized thickness and composition, with the first layer being thin enough to prevent diffusion while maintaining stability, and the second layer providing mechanical support and adhesion control.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite material structures where the first intermediate layer has different chemical composition and properties than the second intermediate layer. The first layer is formulated to be resistant to diffusion of diazo compounds and monomers, while the second layer is formulated for proper adhesion to the relief layer and mechanical stability, creating a composite structure that solves both resolution and stability requirements.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If a thin intermediate layer is used to improve resolution, then halftone dot resolution is improved, but oxygen attack during exposure is intensified

Engineering Contradiction:
Improvehalftone dot resolutionVSAvoidoxygen attack
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The first intermediate layer acts as an intermediary barrier between the recordable template layer and the environment. It is specifically formulated to be resistant to oxygen penetration while maintaining thinness for resolution. This intermediary layer blocks oxygen from reaching the sensitive diazo compounds in the recordable template layer during the exposure process, preventing oxygen attack without requiring thick layers that would compromise resolution.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If a thin intermediate layer is used to improve resolution, then halftone dot resolution is improved, but wrinkling occurs during manufacturing

Engineering Contradiction:
Improvehalftone dot resolutionVSAvoidwrinkling
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

By segmenting the intermediate layer into two separate layers, the patent eliminates wrinkling issues. The second intermediate layer, being in direct contact with the relief layer, provides sufficient thickness and mechanical support to prevent wrinkling during handling and manufacturing. The first intermediate layer remains thin for resolution but is supported by the second layer, preventing wrinkles from forming at the interface with the recordable template layer.

Inventive Principle:
Principle #1Segmentation

4Manufacturing precision

If a thin intermediate layer is used to improve resolution, then halftone dot resolution is improved, but adhesion control becomes difficult

Engineering Contradiction:
Improvehalftone dot resolutionVSAvoidadhesion control
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The segmentation of the intermediate layer into two distinct layers with different adhesion characteristics allows independent optimization of adhesion properties. The second intermediate layer is specifically formulated to provide controlled adhesion to the relief layer, facilitating easy removal of the recordable template layer after exposure. This separation of adhesion functions from the thin first layer enables proper adhesion control without compromising resolution.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves halftone dot resolution, reduces oxygen attack, and ensures easy removal of the template layer, resulting in improved processing and aging resistance of the printing plates, capable of producing high-resolution flexographic printing plates with reduced wrinkles and enhanced uniformity.

Implementation Method 1

a first composite layer (C1) is a barrier layer arranged between the second composite layer (C2) and the recordable template layer (D) against the diazonium compounds contained in the recordable template layer (D)

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

a photopolymerizable layer/relief-forming polymer layer (B) that is soluble in organic and/or aqueous solvents and/or becomes liquid upon heating and/or volatile, and that can be crosslinked by actinic radiation

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 3

a recording-capable template layer (D) comprising a monomeric diazonium compound that is photosensitive to actinic laser radiation and undergoes a change in actinic density by development

Methodology Applied
Scientific EffectPhotochemical reaction: Photo-oxidation

Data Source

PatentEP3832389A1High-resolution flexographic printing plate and means for producing same having improved barrier and adhesion layers
Publication Date: 2021.06.09 FOLEX AG
  • EP3832389A1 patent drawingFigure 1
  • EP3832389A1 patent drawingFigure 2
  • EP3832389A1 patent drawing

AI summary

Described is a recording element suitable for the production of high-resolution flexographic printing plates by digital information transfer and imageable with actinic laser radiation, which contains or consists of the following layers: (A) a carrier film, (B) a photopolymerizable layer/relief-forming polymer layer that can be crosslinked by actinic radiation, (C) an intermediate layer composite transparent to actinic radiation, consisting of at least two polymer-containing layers arranged one above the other, a first composite layer (C1) that acts as a barrier layer, and a second composite layer (C2) that modulates adhesion to the relief-forming polymer layer, (D) a recording-capable template layer comprising a monomeric diazonium compound, and (El) optionally a removable protective or cover film arranged on the recording-capable template layer (D).