Float-Stitch Precious Metal Mesh for Lower N2O Selectivity
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Solution Overview
Problem
Existing knitted precious metal meshes used in catalytic ammonia oxidation processes suffer from high selectivity for the formation of nitrous oxide (N2O), a greenhouse gas, which reduces the yield of the desired nitrogen oxide (NO) and increases environmental impact.
Innovation Solution
A knitted precious metal mesh structure is developed with multiple wires per row, incorporating float stitches to increase density and reduce N2O formation, using platinum or platinum alloys for catalyst meshes and palladium alloys for getter meshes, optimizing the knitting pattern to enhance selectivity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-generated harmful factors
If conventional knitted precious metal meshes are used, then ammonia conversion is achieved, but high selectivity for nitrous oxide formation occurs
Solution Approach 1:
The patent applies local quality by creating non-uniform wire distributions and varying wire diameters within the knitted mesh structure. Different regions of the mesh have different wire densities and configurations, allowing selective promotion of desired catalytic reactions in certain areas while suppressing unwanted side reactions in other areas, thereby reducing nitrous oxide emissions without compromising overall ammonia conversion efficiency
Solution Approach 2:
The patent employs asymmetry by using unequal wire diameters (combining fine wires with diameter 0.02-0.1 mm and coarse wires with diameter 0.1-0.5 mm) and asymmetric knitting patterns. This asymmetric structure creates diverse local catalytic environments that favor the formation of nitrogen monoxide while inhibiting nitrous oxide production, resolving the contradiction between productivity and harmful emissions
2Productivity
If wire density is increased to improve catalytic activity, then ammonia conversion improves, but N2O selectivity increases
Solution Approach 1:
The patent segments the wire structure into two distinct categories: fine wires (0.02-0.1 mm diameter) and coarse wires (0.1-0.5 mm diameter). These segmented wire types are distributed throughout the mesh in specific patterns, with fine wires providing high surface area for catalysis and coarse wires creating larger pores that reduce N2O selectivity. This segmentation allows the mesh to achieve high ammonia conversion while suppressing harmful N2O emissions
Solution Approach 2:
The patent creates a composite wire structure combining different wire diameters and materials (precious metals such as platinum, palladium, rhodium, or their alloys with base metals). This composite approach allows optimization of catalytic activity through fine wires while using coarse wires to control selectivity and reduce N2O formation, effectively resolving the contradiction between productivity and harmful emissions
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The new mesh structure significantly reduces N2O emissions while maintaining high ammonia conversion to NO, improving the efficiency and environmental footprint of nitric acid production.
Implementation Method 1
Precious metal-catalyzed gas reactions, such as the oxidation of ammonia with atmospheric oxygen in nitric acid production (Ostwald process)
Implementation Method 2
the oxidation of ammonia with atmospheric oxygen in nitric acid production (Ostwald process) or the reaction of ammonia with methane in the presence of oxygen to give hydrocyanic acid (Andrussow process)
Implementation Method 3
precious metal catalysts in the form of gas-permeable spatial structures, on or in which the reaction takes place
Data Source
AI summary
The invention relates to a precious metal mesh which is knitted on a flat-bed knitting machine, having at least two float stitches per wale, thus having a significantly higher density for a given latch needle density of the flat-bed knitting machine than the precious metal mesh according to the prior art.


