Floating Electrolyte Cover for Redox Flow Battery Tanks

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Solution Overview

Problem

Oxidation of electrolyte in redox flow battery systems reduces the energy density, as active material ions are consumed, leading to decreased performance.

Innovation Solution

A tank design with a solid cover member floating on the electrolyte surface to inhibit oxidation, combined with a sealed internal space to prevent contact with external oxygen, and a configuration that ensures uniform electrolyte flow.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the electrolyte tank is open to the air, then the ease of operation is improved, but the electrolyte oxidation increases

Engineering Contradiction:
Improveease of operationVSAvoidelectrolyte oxidation
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent applies the inert atmosphere principle by introducing nitrogen gas into the tank headspace to displace oxygen. The nitrogen atmosphere prevents oxidation of the electrolyte while maintaining an open tank configuration for ease of operation. This resolves the contradiction by creating a protective environment that eliminates the harmful oxidative effect without requiring a sealed closed system.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Object-affected harmful factors

If a cover member is added to cover the liquid surface, then the electrolyte oxidation is inhibited, but the device complexity increases

Engineering Contradiction:
Improveelectrolyte oxidationVSAvoiddevice complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

Instead of using a physical cover member that would increase device complexity, the patent employs nitrogen gas to create an inert atmosphere above the electrolyte. This gaseous barrier prevents oxidation without requiring additional mechanical components, thus inhibiting electrolyte oxidation while maintaining simple device architecture.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent uses pneumatic principles by introducing and circulating nitrogen gas within the tank headspace. This gaseous system replaces the need for mechanical cover members, achieving oxidation protection through fluid dynamics rather than solid structures, thereby reducing device complexity.

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Object-affected harmful factors

If the cover member covers 100% of the liquid surface, then the electrolyte oxidation is maximally inhibited, but the manufacturing precision requirements increase

Engineering Contradiction:
Improveelectrolyte oxidationVSAvoidmanufacturing precision
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The nitrogen atmosphere approach eliminates the need for precise positioning of cover members. Since the gas can freely fill the headspace and contact the entire liquid surface without mechanical constraints, oxidation protection is achieved without stringent manufacturing precision requirements for covering components.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent changes the state of the protective barrier from solid (cover member) to gas (nitrogen atmosphere). This parameter change allows the protective medium to conform to the liquid surface without mechanical contact, eliminating the need for precise dimensional matching and positioning that would be required for a solid cover.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The tank effectively inhibits electrolyte oxidation, maintaining high energy density in the redox flow battery system by ensuring minimal contact with oxygen and promoting uniform electrolyte flow.

Implementation Method 1

a cover member, at least a surface of which is solid. The cover member is disposed to float on a liquid surface of the electrolyte stored in the internal space so as to cover the liquid surface

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Data Source

PatentUS20250372674A1Tank and redox flow battery system
Publication Date: 2025.12.04 SUMITOMO ELECTRIC INDUSTRIES LTD
  • US20250372674A1 patent drawing
  • US20250372674A1 patent drawing
  • US20250372674A1 patent drawing

AI summary

A tank for storing an electrolyte in a redox flow battery system includes a tank body which has an internal space separated from the outside, and a cover member, at least a surface of which is solid, wherein the cover member is disposed to float on a liquid surface of the electrolyte stored in the internal space so as to cover the liquid surface, and an area of the liquid surface that is covered by the cover member is 0.90 times or more and 0.99 times or less the entire area of the liquid surface.