Flocculant-Enhanced Solid-Liquid Separation in Enzymatic Hydrolysis

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Solution Overview

Problem

Current methods for solid-liquid separation from hydrolyzed lignocellulosic materials face inefficiencies, particularly in recovering solids with high purity and content, due to the small and lightweight nature of solid particles, which requires the use of flocculants to achieve adequate separation.

Innovation Solution

The method involves adding a flocculant additive, such as a cationic polymer flocculant, to the hydrolyzed material or streams separated from it, followed by decantation or gravitational separation to effectively separate solid and liquid streams, and potentially re-slurrying and re-separating the solids in multiple steps to enhance separation efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional solid-liquid separation methods are used without flocculants, then the process is simpler and faster, but the separation efficiency is poor due to small and lightweight solid particles

Engineering Contradiction:
Improveseparation efficiencyVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

A flocculant additive is introduced as an intermediary substance that mediates between the small solid particles and the separation process. The flocculant binds to the lightweight particles, causing them to aggregate into larger flocs that are much easier to separate using conventional decantation equipment, thus resolving the contradiction between separation efficiency and process complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The addition of flocculant changes the physical parameters of the solid particles in the suspension. It alters their size, density, and aggregation state, transforming them from individual small particles to aggregated flocs with different separation characteristics, enabling effective separation without complex equipment

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If multiple separation steps are performed to improve separation efficiency, then the solid product purity increases, but the process time and complexity increase

Engineering Contradiction:
Improvesolid product purityVSAvoidprocess time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The flocculant is added before the separation process to pre-aggregate the particles. This preliminary action prepares the suspension for more efficient separation, allowing fewer and faster separation steps to achieve the same purity level that would otherwise require many more steps

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The flocculant continuously promotes particle aggregation throughout the separation process, ensuring that particles remain aggregated and separable from start to finish. This continuous action maintains separation efficiency without requiring intermittent intervention or multiple discrete separation operations

Inventive Principle:
Principle #20Continuity of useful action

3Device complexity

If enzymes are not retained in the solid material, then the separation process is simpler, but enzyme recycling is required increasing process complexity

Engineering Contradiction:
Improveprocess simplicityVSAvoidenzyme recycling
Core Design Contradiction:
Device complexityVSLoss of substance

Solution Approach 1:

The flocculant acts as an intermediary that selectively binds to and retains enzymes in the solid fraction during separation. This allows enzymes to be concentrated and retained in the solid product without requiring complex retention equipment, eliminating the need for separate enzyme recycling operations while maintaining process simplicity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves the separation efficiency of solid streams, retains enzymes in the solid material, and reduces enzyme recycling, allowing for the production of solid products with high purity and high solids content, while also simplifying the process and reducing contamination.

Implementation Method 1

adding a flocculant additive to the hydrolyzed material or to a stream separated from the hydrolyzed material to form a mixture

Methodology Applied
Scientific EffectFlocculation: Flocculation

Implementation Method 2

separating a solid stream and a liquid stream from the mixture by means of a decantation or gravitational separation

Methodology Applied
Scientific EffectGravitational separation: Gravitation

Data Source

PatentUS20230279448A1Method and process arrangement for improving a separation and solid product
Publication Date: 2023.09.07 UPM KYMMENE OYJ
  • US20230279448A1 patent drawing
  • US20230279448A1 patent drawing
  • US20230279448A1 patent drawing

AI summary

A method and a process arrangement for improving a solid-liquid separation of solids from a hydrolyzed material formed in an enzymatic hydrolysis of lignocellulosic material, comprising following step: i) adding a flocculant additive to the hydrolyzed material or to a stream separated from the hydrolyzed material to form a mixture, and ii) separating a solid stream and a liquid stream from the mixture by means of a decantation or gravitational separation. Further is disclosed a solid product.