Flow Cell Particle Analysis via Optical Detection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current on-line measurement techniques for industrial liquids containing solid matter, such as those in the forest, oil, and water treatment industries, face challenges like time delays in off-line methods and lack of accuracy in on-line methods, along with issues like flocculation and mechanical/chemical sticking in fractionation systems, which hinder effective monitoring of particle size and hydrophobicity.

Innovation Solution

A robust on-line system utilizing field flow fractionation with a disintegration channel and optical measurements, where a sample is stained with a dye and fractionated based on particle size and mass, allowing for continuous monitoring of hydrophobic/hydrophilic particles, and extracting key variables like particle counts and hydrophobicity using light scattering and fluorescence signals.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If off-line batch sampling and laboratory analyses are used, then measurement accuracy is improved, but time delay increases

Engineering Contradiction:
Improvemeasurement accuracyVSAvoidtime delay
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent replaces manual mechanical laboratory analysis with automated optical measurement systems that use light scattering and fluorescence detection to measure particle properties in real-time, eliminating the need for manual sample preparation and laboratory processing while maintaining measurement accuracy

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system performs self-measurement by incorporating all necessary measurement functions directly into the process line, where the measurement device automatically analyzes particles as they flow through the system without requiring external laboratory intervention or manual sample handling

Inventive Principle:
Principle #25Self-service

2Loss of time

If on-line measurement methods are used, then response time is improved, but measurement accuracy deteriorates

Engineering Contradiction:
Improveresponse timeVSAvoidmeasurement accuracy
Core Design Contradiction:
Loss of timeVSMeasurement precision

Solution Approach 1:

The patent introduces flow cells as intermediary structures that allow particles to pass through in a controlled manner, enabling on-line measurement while maintaining accuracy by ensuring particles are properly positioned and illuminated for optical detection without requiring manual intervention

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The system changes the measurement parameters by using multiple optical detection methods (light scattering at different angles, fluorescence detection) simultaneously to capture comprehensive particle information, allowing accurate on-line measurement of particle size, concentration, and properties without manual analysis

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If fractionation techniques are used, then particle separation is improved, but mechanical sticking and chemical sticking occur

Engineering Contradiction:
Improveparticle separationVSAvoidmechanical sticking and chemical sticking
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent extracts particles from the bulk flow into separate flow cells for individual measurement, removing them from the environment that causes sticking, and measuring them in isolation where their optical properties can be detected without interference from aggregation or adhesion to surfaces

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system replaces mechanical fractionation methods that cause particle sticking with optical detection methods that measure particles in situ, using light scattering and fluorescence to characterize particles without requiring physical separation or contact with surfaces that would cause adhesion

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate, real-time monitoring of particle properties in industrial liquids, overcoming limitations of existing methods by providing detailed information on particle size distribution and hydrophobicity without the need for manual pre-treatment, suitable for continuous operation and effective process control.

Implementation Method 1

a dye is added to the sample to stain the particles contained therein

Methodology Applied
Scientific EffectAbsorption (physical): Absorption (physical)

Implementation Method 2

a disintegration channel with a liquid flow having a non-constant temporal velocity profile... causing fractioning of the sample particles

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Implementation Method 3

The sample can be fractionated, pretreated or untreated... by fractionation, or by settling or centrifugation, e.g. according to the mass or size (or both) of the particles

Methodology Applied
Scientific EffectCentrifugal force: Centrifugal Force

Implementation Method 4

extracting key variables like particle counts and hydrophobicity using light scattering and fluorescence signals

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 5

extracting key variables like particle counts and hydrophobicity using light scattering and fluorescence signals

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentEP3071955B1A method and system for analyzing a liquid sample containing particles of solid matter and the use of such a method and system
Publication Date: 2020.01.01 KEMIRA OY
  • EP3071955B1 patent drawingFigure 1~3
  • EP3071955B1 patent drawingFigure 4~5
  • EP3071955B1 patent drawingFigure 6~7

AI summary

The invention relates to a method and system for monitoring of particles properties in a stream and the use of such method and system. In particular, the invention concerns sampling of liquids like aqueous suspensions or filtrates that contain solid matter in forest industry, oil and mining industry, as well as in and water treatment, desalination or water reuse processes, and in subsequent measurement of the samples. A sample from a stream of liquid is dyed to stain particles contained in the sample, which is conducted to a first flow chamber (23) having means for causing said sample to be divided into particle populations according to their size or mass. A liquid flow is applied through the first flow chamber to cause at least one particle population to flow into a second flow chamber (24). The particle populations are measured to produce at least one measurement signal representative of the amount and/or properties of the particles, and processing extract key variables of each particle population and presenting them as an analysis of particle populations or the whole sample in terms of a count and size of particles and/or their hydrophobicity.