Fuel Cell Flow Field Plate Coating for Corrosion and Conductivity

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Solution Overview

Problem

Flow field plates in proton-exchange membrane fuel cells are susceptible to corrosion in acidic environments, leading to degradation and increased costs, as existing coatings do not adequately protect these components while maintaining functional performance.

Innovation Solution

A method involving the application of a protective coating material selected based on adsorption energies and electronic conductivity, using computational methods like DFT to identify suitable materials and deposition techniques, such as solution-based or atomic layer deposition, to form a barrier that prevents corrosion and supports electron transfer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a coating is applied to protect the flow field plate from corrosion, then corrosion resistance is improved, but electronic conductivity may deteriorate

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidelectronic conductivity
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies parameter changes by controlling the thickness of the coating layer (maintaining it below 10 micrometers, preferably 1-5 micrometers) and adjusting the metal content concentration in the solution (0.1-10 wt%). These parameter optimizations ensure the coating provides sufficient corrosion protection while maintaining electronic conductivity for fuel cell operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining metal-containing precursors (such as metal salts or metal organics) with organic binders and solvents to create a coating composition. This composite structure allows the coating to provide both corrosion protection and electrical conductivity, resolving the contradiction between protection and energy loss.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a thick coating is applied to enhance protection, then corrosion resistance is improved, but manufacturing precision and functional performance deteriorate

Engineering Contradiction:
Improvecorrosion protectionVSAvoidcoating thickness control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent specifies precise parameter ranges: coating thickness controlled at 1-10 micrometers (preferably 2-5 micrometers), and metal content at 0.1-10 wt% (preferably 1-5 wt%). These controlled parameters ensure adequate protection without excessive thickness that would compromise manufacturing precision or fuel cell performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies partial action by using a thin coating layer (1-10 micrometers) rather than a thick coating, which is sufficient to provide corrosion protection while avoiding the negative effects of excessive thickness. This partial application maintains manufacturing precision and functional performance.

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If existing coating materials are used, then some protection is provided, but pinhole formation occurs and protection is inadequate

Engineering Contradiction:
Improvecorrosion protectionVSAvoidpinhole formation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses composite materials by formulating a coating containing metal-containing precursors combined with organic binders and solvents. This composite composition creates a more uniform and defect-free coating structure that prevents pinhole formation while providing adequate corrosion protection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes parameters including metal content concentration (0.1-10 wt%), coating thickness (1-10 micrometers), and drying/heat treatment conditions. These parameter optimizations ensure complete coverage and uniform coating formation, eliminating pinholes and providing effective corrosion protection.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The selected coatings effectively reduce corrosion, prevent pinhole formation, and maintain electronic conductivity, thereby extending the lifecycle and reducing costs of flow field plates.

Implementation Method 1

evaporating the solvent to form a coating on the at least the portion of the surface of the flow field plate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

calculating one or more adsorption energies of one or more reactive elements, respectively, on a plurality of coating materials

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11377738B2Method of applying a flow field plate coating
Publication Date: 2022.07.05 ROBERT BOSCH GMBH
  • US11377738B2 patent drawing
  • US11377738B2 patent drawing
  • US11377738B2 patent drawing

AI summary

A method of applying a coating to a flow field plate of a fuel cell. The method includes applying a solution including a metal-containing precursor and a solvent to at least a portion of a surface of a flow field plate, and evaporating the solvent to form a coating on the at least the portion of the surface of the flow field plate.