Predictive Control of Flue Gas Desulfurization for SO2 Removal

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Solution Overview

Problem

Conventional air pollution control systems, such as wet flue gas desulfurization (WFGD) and selective catalytic reduction (SCR), face challenges in optimizing SO2 and NOx removal efficiency while maintaining gypsum quality and minimizing operational costs, due to limitations in process control strategies and lack of real-time measurement of critical parameters like pH and ammonia slip.

Innovation Solution

A model-based multivariable predictive control (MPC) system is implemented, which uses neural network or non-neural network models to predict the effects of process parameter changes on emissions and byproduct quality, allowing for optimized control of limestone slurry pH, ammonia flow, and oxidation air distribution to achieve dynamic balance between SO2 removal, gypsum quality, and operational costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional process control strategies are used in WFGD and SCR systems, then operational simplicity is maintained, but SO2 and NOx removal efficiency cannot be optimized while maintaining byproduct quality

Engineering Contradiction:
ImproveSO2 and NOx removal efficiencyVSAvoidprocess control strategy complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The system performs preliminary actions by predicting future emissions and byproduct quality parameters using process models before actual changes occur. The optimizer calculates optimal setpoints in advance based on predicted responses to control parameter adjustments, allowing the system to proactively maintain efficiency and quality rather than reactively responding to deviations.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The control system transitions from static conventional control to dynamic model-based predictive control. The process models dynamically predict emissions and gypsum quality responses to parameter changes, and the optimizer dynamically adjusts setpoints based on current operating conditions, market values of regulatory credits, and predicted future states, enabling adaptive optimization of removal efficiency.

Inventive Principle:
Principle #15Dynamics

2Productivity

If real-time adjustment of process parameters is implemented to optimize emissions removal, then SO2 and NOx removal efficiency improves, but operational costs increase

Engineering Contradiction:
Improveemissions removal efficiencyVSAvoidoperational costs
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The system optimizes process parameters (limestone slurry pH, ammonia flow rate, oxidation air distribution) to achieve the desired balance between emissions removal and operational costs. By precisely controlling these parameters based on model predictions and economic objectives, the system maximizes removal efficiency while minimizing energy consumption and reagent usage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system implements closed-loop feedback control where actual emissions measurements and byproduct quality data are continuously compared against predicted values. The optimizer uses this feedback along with market values of regulatory credits to adjust setpoints, ensuring that operational costs are minimized while maintaining compliance and optimizing removal efficiency over time.

Inventive Principle:
Principle #23Feedback

3Reliability

If limestone slurry pH is increased to prevent limestone blinding, then reliability improves, but gypsum quality deteriorates

Engineering Contradiction:
Improveprevention of limestone blindingVSAvoidgypsum quality
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The process model predicts the response of both limestone blinding risk and gypsum quality to pH adjustments before changes are implemented. The optimizer uses these predictions to determine the optimal pH setpoint that prevents blinding while maintaining gypsum quality specifications, avoiding the need for conservative over-correction that would degrade quality.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The system dynamically adjusts the limestone slurry pH parameter based on real-time conditions, balancing the competing objectives of preventing limestone blinding and maintaining gypsum quality. By optimizing pH rather than maintaining a fixed conservative value, the system achieves reliability without sacrificing manufacturing precision of the gypsum byproduct.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If aggressive control actions are taken to meet rolling-average emissions limits, then emissions compliance improves, but byproduct quality and operational stability deteriorate

Engineering Contradiction:
Improverolling-average emissions complianceVSAvoidoperational stability and byproduct quality
Core Design Contradiction:
Object-affected harmful factorsVSStability of the object's composition

Solution Approach 1:

The system performs preliminary optimization by predicting future emissions trajectories and their impact on rolling-average compliance. The optimizer calculates optimal setpoints in advance that achieve compliance objectives while maintaining operational stability and byproduct quality, avoiding aggressive reactive control actions that would cause instability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The dynamic predictive control system continuously adapts setpoints based on current emissions rates, predicted future emissions, and rolling-average limit requirements. This dynamic adjustment enables smooth, stable control actions that achieve compliance without the abrupt changes and operational instability associated with aggressive conventional control strategies.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The MPC system enhances SO2 removal efficiency, maintains gypsum quality, and minimizes operational costs by automatically adjusting process parameters based on real-time data and market values of regulatory credits, effectively managing rolling-average emissions and preventing limestone blinding.

Implementation Method 1

The controller includes a neural network process model or a non-neural network process model... The control processor is configured with the logic to predict, based on the one model, how changes to a current value of each of at least one of the CTPPs will affect a future AV of emitted AOP

Methodology Applied
Scientific EffectNeural network prediction:

Implementation Method 2

A model-based multivariable predictive control (MPC) system is implemented, which uses neural network or non-neural network models to predict the effects of process parameter changes on emissions and byproduct quality

Methodology Applied
Scientific EffectModel-based predictive control:

Implementation Method 3

wet and dry flue gas desulfurization (WFGD/DFGD)... oxidation air distribution to achieve dynamic balance between SO2 removal

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 4

wet flue gas desulfurization (WFGD)... control of limestone slurry pH... to achieve dynamic balance between SO2 removal

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 5

selective catalytic reduction (SCR)... control of ammonia flow... to achieve dynamic balance between NOx removal

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS7640067B2Estimated parameter based control of a process for controlling emission of a pollutant into the air
Publication Date: 2009.12.29 GE VERNOVA INFRASTRUCTURE TECHNOLOGY LLC
  • US7640067B2 patent drawing
  • US7640067B2 patent drawing
  • US7640067B2 patent drawing

AI summary

A controller directs a process primarily performed to control emission of a particular pollutant into the air. The process has multiple process parameters (MPPs), including a parameter representing an amount of the particular pollutant. The controller includes either a neural network process model or a non-neural network process model. In either case, the model represents a relationship between a first of the MPPs and one or more of the other MPPs. The one or more other MPPs include a second of the MPPs which is other than the parameter representing the amount of the emitted particular pollutant. Also included is a processor configured with logic to estimate a value of the second MPP, and to direct control of the first MPP based on the estimated value of the second MPP and the model.