Fluid-Assisted Device Transfer on Non-Conventional Substrates

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Solution Overview

Problem

Existing methods for fabricating electronic, optoelectronic, and magnetic devices on non-conventional substrates face challenges such as poor yield and area size restrictions due to difficulties in directly transferring devices from conventional substrates.

Innovation Solution

A device fabrication method involving a growth substrate with an oxide layer, a metal layer, and a stack of device layers, where fluid-assisted interfacial debonding is used to separate the device layers from the substrate, allowing for transfer to a target substrate, including non-conventional materials like paper, plastics, and metal foils.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional transfer techniques are used to fabricate devices on non-conventional substrates, then device transfer is enabled, but yield is poor and area size is restricted

Engineering Contradiction:
Improvedevice transfer yieldVSAvoidtransfer quality
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces an intermediary liquid medium (water or other fluids) that facilitates the debonding process at the metal-oxide interface. This fluid mediator enables stress-free separation of the device stack from the growth substrate, significantly improving transfer yield and quality compared to conventional mechanical peeling methods.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical-chemical parameters of the interface by introducing a liquid fluid that alters the interfacial energy and bonding characteristics. This parameter change enables controlled debonding at specific interfaces (metal-oxide) while maintaining adhesion elsewhere, resolving the contradiction between transfer yield and transfer quality.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If direct fabrication on non-conventional substrates is attempted, then substrate versatility is improved, but fabrication difficulty increases

Engineering Contradiction:
Improvesubstrate compatibilityVSAvoidfabrication complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent segments the fabrication process into two independent stages: (1) device fabrication on conventional growth substrates using standard techniques, and (2) transfer to non-conventional substrates using fluid-assisted debonding. This segmentation allows each stage to be optimized independently, maintaining ease of manufacture while achieving substrate versatility.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The fluid-assisted transfer process acts as an intermediary mechanism that decouples the fabrication process from the final substrate requirements. This intermediary transfer step enables the use of diverse non-conventional substrates without complicating the actual device fabrication process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Speed

If mechanical peeling is used for transfer, then transfer speed is improved, but mechanical stress damages devices

Engineering Contradiction:
Improvetransfer rateVSAvoiddevice integrity
Core Design Contradiction:
SpeedVSStrength

Solution Approach 1:

The patent replaces the mechanical peeling system with a chemically-assisted separation system using fluid-mediated debonding. This substitution eliminates high mechanical stresses that damage devices while maintaining efficient transfer rates, as the fluid penetrates and weakens interfacial bonds chemically rather than relying on forceful mechanical separation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the debonding mechanism from mechanical force to fluid-mediated interfacial energy modification. This parameter change allows rapid transfer by reducing the energy barrier for separation at the metal-oxide interface, achieving high transfer rates without the mechanical stress that would damage device structures.

Inventive Principle:
Principle #35Parameter changes

4Strength

If thermal processing is used for transfer, then bond breaking is improved, but thermal stress distorts devices

Engineering Contradiction:
Improveinterface separationVSAvoiddevice geometry
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent substitutes thermal processing with fluid-assisted chemical debonding. This replacement achieves effective interface separation through fluid-mediated interfacial energy changes rather than thermal bond breaking, eliminating thermal stress that would cause device distortion while maintaining effective separation capability.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the separation mechanism from thermal energy input to fluid-mediated interfacial energy modification. This parameter change enables effective bond breaking at the metal-oxide interface through chemical and surface energy effects rather than thermal expansion and stress, preserving device geometry while achieving interface separation.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables cost-effective, high-yield transfer of devices with minimal mechanical and thermal stress, maintaining original device properties and geometries, and allowing for diverse substrate applications, including flexible and conformal technologies.

Implementation Method 1

performing fluid-assisted interfacial debonding of the metal layer to separate the stack of device layers and the metal layer from the growth substrate

Methodology Applied
Scientific EffectFluid-assisted interfacial debonding: Wetting

Data Source

PatentUS9337169B2Environmentally-assisted technique for transferring devices onto non-conventional substrates
Publication Date: 2016.05.10 THE BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIV
  • US9337169B2 patent drawing
  • US9337169B2 patent drawing
  • US9337169B2 patent drawing

AI summary

A device fabrication method includes: (1) providing a growth substrate including an oxide layer; (2) forming a metal layer over the oxide layer; (3) forming a stack of device layers over the metal layer; (4) performing fluid-assisted interfacial debonding of the metal layer to separate the stack of device layers and the metal layer from the growth substrate; and (5) affixing the stack of device layers to a target substrate.