Fluidised Bed Scrubber CO2 Capture Without Amines

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Solution Overview

Problem

Current carbon capture methods require expensive reagents and energy-intensive processes to absorb and release CO2 from flue gas streams, limiting efficiency and increasing costs.

Innovation Solution

The use of counter-current fluidised bed gas scrubbers with non-reacting salt or saline solutions, such as brackish water, to capture CO2 without the need for amines or carbonates, leveraging high liquid-to-gas ratios and unique fluidised bed properties to achieve high capture efficiencies.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If chemical reactions with amines or carbonates are used to enhance CO2 absorption, then CO2 capture efficiency is improved, but the cost of reagents and energy for reversing the reaction increases

Engineering Contradiction:
ImproveCO2 capture efficiencyVSAvoidenergy for reversing reaction
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The invention extracts the CO2 absorption function from reactive chemical systems (amines, carbonates) and transfers it to a physical absorption system using salt solutions. The salt solution absorbs CO2 physically without forming strong chemical bonds, eliminating the need for energy-intensive reaction reversal processes while maintaining high capture efficiency

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the fundamental parameter of the absorption mechanism from chemical reaction-based to physical dissolution-based. By using salt solutions with high ionic strength, the system achieves enhanced physical absorption of CO2 without the need for subsequent chemical reversal, thereby reducing energy consumption

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If packed towers or sieve plate columns are used to achieve high L/G ratios, then CO2 absorption capacity is improved, but flooding occurs

Engineering Contradiction:
ImproveCO2 absorption capacityVSAvoidflooding
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The invention uses a fluidised bed of hollow plastic elements that create a porous, high-surface-area structure for gas-liquid contact. This porous structure allows high liquid-to-gas ratios to be maintained without flooding, as the fluidised bed dynamically adjusts to accommodate the liquid flow while providing extensive interfacial area for CO2 absorption

Inventive Principle:
Principle #31Porous materials

3Loss of energy

If spray towers are used to achieve high L/G ratios, then pressure loss is reduced, but insufficient interphase surface area is generated

Engineering Contradiction:
Improvepressure lossVSAvoidinterphase surface area
Core Design Contradiction:
Loss of energyVSArea of stationary object

Solution Approach 1:

The invention employs a dynamic fluidised bed system where hollow plastic elements are continuously suspended and mixed by upward gas flow. This dynamic state creates constantly renewing interphase surface area between the liquid and gas phases, maintaining high absorption capacity while allowing liquid to fall freely and minimize pressure loss

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves CO2 capture efficiencies exceeding 50% without the need for costly reagents or energy, facilitating efficient CO2 release and reuse in applications like Enhanced Oil Recovery and horticultural growth, while avoiding flooding and pressure loss issues.

Implementation Method 1

a more advantageous result is achieved by combining the unique properties of counter-current fluidised bed gas scrubbers with the use of non-reacting salt or saline solutions

Methodology Applied
Scientific EffectPhysical absorption: Absorption (physical)

Implementation Method 2

Salting out (precipitation of salts above the solubility limit) will not block the fluidised bed

Methodology Applied
Scientific EffectSalting out: Precipitation

Implementation Method 3

counter-current fluidised bed gas scrubbers, which employ fluidisable elements

Methodology Applied
Scientific EffectFluidisation: Fluidisation

Implementation Method 4

Generation of high interfacial areas particularly with eccentric shapes

Methodology Applied
Scientific EffectInterfacial area generation:

Implementation Method 5

combining the unique properties of counter-current fluidised bed gas scrubbers

Methodology Applied
Scientific EffectCounter-current flow:

Implementation Method 6

high interfacial areas particularly with eccentric shapes

Methodology Applied
Scientific EffectMass transfer: Diffusion

Data Source

PatentEP3277407B1Process for the absorption of carbon dioxide
Publication Date: 2021.06.16 FLUID TECH ENVIRONMENTAL
  • EP3277407B1 patent drawingFigure 1
  • EP3277407B1 patent drawingFigure 2
  • EP3277407B1 patent drawingFigure 3

AI summary

In one proposed application provided by the present invention, and as shown in Figure 2, CO2 is captured from a dirty flue gas in a fluid bed TurboscrubberRTM to be recycled rapidly to a fluid bed TurbostripperRTM where it is desorbed into a clean air stream for introduction to a horticultural glass-house for enhancement of fruit, vegetable or other crop growth. In a further application of the present invention as shown in Figure 3, CO2 enriched saltwater is circulated through a tank (7), to feed Algae thereby allowing fast photosynthesis to occur in, for example, the production of bio fuels. Alternatively, if the Algae suspension is sufficiently robust, it can be pumped around a TurboscubberRTM (2) and the Algae tank (7) in order to keep it in constant contact with the CO2 enriched aqueous solution.