Fluidized Bed Catalyst Circulation for Methane Synthesis Heat Control

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Solution Overview

Problem

Existing methods for controlling heat in methane synthesis reactions, such as those used in Synthetic Natural Gas (SNG) production, face challenges with catalyst overheating, leading to reduced methane yield and inefficient heat management, particularly in fixed bed reactors which are complex and difficult to maintain.

Innovation Solution

A system comprising a first fluidized bed reactor for producing product gas and a second fluidized bed reactor for catalyst heat exchange, allowing for efficient heat and mass transfer, catalyst recovery, and uniform temperature distribution by circulating catalyst particles between the two reactors.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a fixed bed reactor is used for methane synthesis, then the catalyst can be easily manufactured in tablet or pallet form, but the heat generated by the reaction is stored from the starting region causing non-uniform temperature distribution and catalyst overheating

Engineering Contradiction:
Improvecatalyst manufacturingVSAvoidtemperature distribution uniformity
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent transitions from a static fixed bed reactor to a dynamic fluidized bed reactor where catalyst particles are continuously circulated between the reaction zone and cooling zone. This dynamic circulation prevents heat accumulation and achieves uniform temperature distribution throughout the catalyst bed.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent introduces an intermediate cooling zone that acts as a heat exchange mediator between the reaction zone and the catalyst. The cooling zone receives hot catalyst particles from the reaction zone, cools them down, and returns the cooled particles to the reaction zone, effectively managing heat distribution.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Temperature

If multiple reactors are used to control heat of methanation reaction, then the heat control is improved, but the system complexity increases with many reactors, heat exchangers, and gas re-circulation systems

Engineering Contradiction:
Improveheat control efficiencyVSAvoidsystem complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The patent combines the reaction zone and cooling zone into a single integrated fluidized bed reactor system. The catalyst particles themselves serve as the heat transfer medium, eliminating the need for separate heat exchangers and gas re-circulation systems required in traditional multi-reactor configurations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The catalyst particles perform multiple functions simultaneously: they catalyze the methanation reaction in the reaction zone and serve as heat carriers to the cooling zone. This multi-functionality simplifies the overall system by eliminating dedicated heat exchanger equipment.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Temperature

If a fluidized bed reactor is used, then heat and mass transfer is improved with uniform temperature distribution, but the system design becomes more complex compared to fixed bed reactors

Engineering Contradiction:
Improvetemperature distribution uniformityVSAvoidreactor design complexity
Core Design Contradiction:
TemperatureVSDevice complexity

Solution Approach 1:

The catalyst particles self-regulate their temperature through continuous circulation between the hot reaction zone and the cooler cooling zone. The system uses the catalyst itself as the heat transfer medium, eliminating the need for complex external cooling systems and achieving uniform temperature distribution automatically.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration achieves high methane yield, effective heat control, and simplifies catalyst recovery and replenishment, compared to traditional fixed bed reactors, while maintaining a simple system design.

Implementation Method 1

a second reactor configured to cool a catalyst discharged from the first reactor

Methodology Applied
Scientific EffectHeat exchange: Heat Exchanger

Implementation Method 2

the catalyst is circulated between the first reactor and the second reactor

Methodology Applied
Scientific EffectCatalyst circulation: Convection

Data Source

PatentUS9963400B2System and method for preventing catalyst from overheating
Publication Date: 2018.05.08 KOREA INST OF ENERGY RES
  • US9963400B2 patent drawing
  • US9963400B2 patent drawing
  • US9963400B2 patent drawing

AI summary

A system for preventing a catalyst from overheating is provided. The system includes: a first reactor filled with a catalyst at least in part and configured to receive reaction gas and produce product gas; and a second reactor configured to cool a catalyst discharged from the first reactor. The catalyst is circulated between the first reactor and the second reactor by injecting the catalyst cooled in the second reactor into the first rector.