Fluidized Bed Coking With Weak Acid Heat Carrier

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Solution Overview

Problem

Current coking processes face challenges in maximizing liquid yields while minimizing coke yields, particularly when processing heavy hydrocarbon feedstocks with high Conradson Carbon Residue, metals like Nickel and vanadium, and Asphaltenes, due to limitations in heat carrier efficiency and acid site strength.

Innovation Solution

A process employing a high heat carrier with weak acid sites, using modified clays like kaolinite, bentonite, and montmorillonite, to crack heavy hydrocarbons at temperatures between 480°C to 620°C, with the feedstock being dispensed as an atomized spray, allowing for a controlled residence time to achieve a product comprising 70-80% hydrocarbons with boiling points between 40-600°C, and regenerating the particulate material to 10-30% for continuous operation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If delayed coking process is used to process heavy hydrocarbon feedstock, then coke yield is produced, but liquid yield is not maximized and batch time is prolonged

Engineering Contradiction:
Improveliquid yieldVSAvoidbatch time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent replaces the conventional delayed coking mechanical batch process with a fluidized bed reactor system that uses fluid dynamics and heat carrier particles to achieve continuous processing. The feedstock is contacted with hot particles in a fluidized bed, enabling continuous operation rather than batch processing, thus reducing batch time while maximizing liquid yield through optimized residence time and heat transfer.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If conventional thermal cracking is used, then cracking reactions occur, but heat transfer efficiency is insufficient and coke yield increases

Engineering Contradiction:
Improvecracking efficiencyVSAvoidheat transfer efficiency
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The patent introduces heat carrier particles as an intermediary medium between the heat source and the hydrocarbon feedstock. These particles absorb and store thermal energy, then transfer it efficiently to the feedstock during fluidized bed contact. This intermediary heat transfer mechanism significantly improves heat transfer efficiency compared to direct thermal cracking, reducing energy loss and optimizing cracking efficiency while controlling coke yield.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If strong acid sites are used in catalytic cracking, then cracking activity increases, but deactivation by metals and asphaltenes occurs rapidly

Engineering Contradiction:
Improvecracking activityVSAvoidcatalyst stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the acidity parameter of the catalyst from strong acid sites to weak acid sites. This parameter change reduces the catalyst's susceptibility to deactivation by metals and asphaltenes while maintaining adequate cracking activity. The weak acid sites provide sufficient catalytic function for cracking heavy hydrocarbons into liquid products without the rapid deactivation problems that plague strong acid catalysts when processing contaminated feedstocks.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If fluid coking is used to reduce volatile matter in coke, then coke quality improves, but process complexity increases

Engineering Contradiction:
Improvecoke qualityVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functions into a single fluidized bed reactor: thermal cracking, catalytic cracking, and coke formation all occur simultaneously in one unit. The heat carrier particles serve multiple purposes - providing heat, acting as a catalyst support, and enabling continuous operation. This multi-functional approach achieves improved coke quality through continuous processing and optimized residence time without requiring the complex multi-stage configuration of conventional fluid coking processes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases liquid yields by 10-20% and reduces coke yields by 10-20%, effectively processing feedstocks with high CCR content, enhancing refinery efficiency and profitability.

Implementation Method 1

The feedstock is vaporized and brought in contact with a heat carrier material

Methodology Applied
Scientific EffectHeat transfer: Conduction (thermal)

Implementation Method 2

regeneration of the particulate heat carrier

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

cracking heavy hydrocarbon feedstock employing high heat carrier

Methodology Applied
Scientific EffectThermal cracking: Pyrolysis

Data Source

PatentUS9944862B2Process and a system for enhancing liquid yield of heavy hydrocarbon feedstock
Publication Date: 2018.04.17 INDIAN OIL CORP LTD
  • US9944862B2 patent drawing
  • US9944862B2 patent drawing

AI summary

The present invention provides a process and a system for coking and simultaneous upgrading of a heavy hydrocarbon feedstock. More particularly the present invention relates to a process of cracking heavy hydrocarbon feedstock employing high heat carrier, incorporated with weak acid sites for improving the liquid yield and reducing coke yield. The feedstock is vaporized and brought in contact with a heat carrier material to produce a product stream and separating the product stream from the particulate heat carrier, regeneration of the particulate heat carrier to the extent of 10-30% and collecting a gaseous and liquid product from the product stream.